金属络合物不对称催化硫醚氧化研究现状

Research Statues on Metal Complex Catalytic Asymmetric Oxidation of Sulfides

手性亚砜是重要的手性中间体和辅剂、手性配体和催化剂、手性药物。手性金属络合物催化硫醚的不对称氧化是合成手性亚砜最有效的方法。文章简要的介绍了钛,钒,铌,铁四种金属的络合物不对称催化硫醚氧化的一些最新的研究现状。

Chiral sulfoxides and their derivatives are important chiral intermediates and auxiliaries,chiral ligands and catalysts,and chiral drugs.The most efficient way to generate chiral sulfox ides is asymmetric oxidation of prochir al sulfides catalyzed by chiral metal complexes.The paper briefly described the titanium,vanadium,Niobium,Iron of four metals of catalytic asymmetric sulfide oxidation status of some of the latest research.