摘要
本文应用Pitzer理论,在25℃,0～6mol/kg浓度范围内,计算了二十种1-1价,1-2价,2-1价,3-1价,4-1价的单个电解质水溶液的平均活度系数,计算结果与文献值符合得很好。最后对影响高价电解质计算结果的因素进行了讨论。
Pitzer's theory is used for calculating mean activity coefficients of pure aqueous electrolytes over the range from 0 to 6 mol/kg at 25℃. Results given for 20 electrolyte of 1-1, 1-2, 2-1, 3-1, and 4-1 valence types are in good agreement with those from literatures. A discussion about results of high valence types is given at the end.
出处
《西安工业学院学报》
1990年第2期1-8,共8页
Journal of Xi'an Institute of Technology
关键词
电解质
活度系数
水溶液
热力学
Pitzer's theory
electrolyte
mean activity coefficient
aqueous solution
