从盐-水-酰胺体系相图研究中获得新配合物

ACQUISITION OF NEW COMPOUNDS IN THE STUDY OF PHASE DIAGRAM FOR SALT-WATER-AMIDE SYSTEM

在盐-水-酰胺体系的相图研完中,得到一系列配合物,其中有些配合物是合成法不易制备的。本文报道从三元体系LiCl-CH_3CONH_2-H_2O和M_gCl_2-H_2O-CH_3CON(CH_3)_2[CH_3CON(CH_3)_2简称DMA]中制取LiCl·2CH_3CONH_2·H_2O,LiCl·CH_3CONH_2·H_2O和MgCl_2·2DMA·6H_2O配合物的研完,并对这些配合物用红外、热分析和结构分析进行了验证。

The acquisition of a series of new compounds in the study of phase diagram for salt-water-amide system is much an easier way than aythetie preparation for the same compounds, This paper covers the acquisition of the coordination compounds such as LiCl·2CH_3CONH_2·H_2O, LiCl·CH_3CONH_2·H_2O and MgCl_2·2DMA·6H_2O from LiCl-CH_3CONH_2-H_2O and MgCl_2-H_2O-CH_3CON(CH_3)_2[DMA]; and the rectification of the results of the compounds' analysis through infrared, heat and structure.