摘要
合成了稀土元素铈钼钒磷四元杂多配合物(NH4)15[Ce(PMo9V2O39)2]·5H2O.研究了其对乙苯选择性氧化合成苯乙酮的催化活性,并探讨了溶剂、温度、H2O2 与乙苯的摩尔比对该反应的影响.
The cerium molybdovanadlphosphoric tetrabasic heteropoly complex was synthesized.Catalysis of the title heteropoly complex for selective oxidation of ethylbenzene to acetophenone was investigated.The effects of solvent,temperature, H 2O 2∶ethylbenzene (molar ratio) on the catalytic activity were also discussed.
出处
《福建师范大学学报(自然科学版)》
CAS
CSCD
1999年第4期49-52,共4页
Journal of Fujian Normal University:Natural Science Edition
基金
福建省科委资助
关键词
催化
杂多配合物
苯乙酮
过氧化氢
乙苯
氧化
catalysis , cerium , heteropoly complex ,acetophenone, hydrogen peroxide