对硝基苯乙酮缩氨基硫脲Cu(Ⅱ)、Fe(Ⅱ)、Zn(Ⅱ)配合物的直接电化学合成

The Direct Electrochemical Synthesis of Cu(Ⅱ),Fe(Ⅱ),Zn(Ⅱ) Complexes of p-Nitroacetophenone Thiosemicarbazone

本文在以对硝基苯乙酮缩氨基硫脲 (HL)为配体的非水溶剂中 ,用Cu、Fe、Zn金属做阳极 ,首次用电化学金属阳极氧化法合成了对硝基苯乙酮缩氨基硫脲 (HL)与Cu (Ⅱ )、Fe (Ⅱ )、Zn (Ⅱ )的金属配合物 ,通过元素分析、红外光谱、紫外光谱。

The metal complexes of Cu(Ⅱ),Fe(Ⅱ),Zn(Ⅱ) were synthesized by the electrochemical oxidation method of Cu,Fe,Zn anodic metal in non-aqueous solvent containing p-nitroacetophenone thiosemicarbazone.The complexes were characterized by elemental analysis,IR,UV,and molar conductivity.