摘要
采用离子交换法将三种季铵盐,十烷基三丁基溴化铵(DTBA),十二烷基三丁基溴化铵(DDTBA),十四烷基三丁基溴化铵(TDTBA)交换到层状α-磷酸锆(α-ZrP)的层间得到季铵盐柱撑鏻酸锆,考察了季铵盐的种类和用量对季铵盐改性磷酸锆的结构、形态、热稳定性和长效抗菌性能的影响。结果显示季铵盐已经成功插入层状α-磷酸锆的层间,且改性磷酸锆的层间距随着季铵盐烷基链的增加而增大。季铵盐含量为21.8 mass%的DDTBA-ZrP1.0显示良好的耐热性、耐水性和长效抗菌性能。
Layered α-Zirconium phosphate（α-ZrP）was exchanged with three quaternary alkylammonium salts,decyl tributylammonium bromide（DTBA）,dodecyl tributylammonium bromide（DDTBA）and Tetradecyl tributyl-ammonium bromide（TDTBA）,to investigate the effects of ammonium salts species and usage on the characteristics,morphology,thermal stability and long-acting antibacterial property of quaternary alkylammonium salts pillared α-Zirconium phosphate（DZrP）.The results show that the ammonium salts are intercalated into α-ZrP,and the basal spacing of D-ZrP was enlarged with the increasing of ammonium salt content or the growing of alkyl chain length.DDTBA-ZrP1.0 with 21.8 mass%of dodecyl tributyl ammonium salt displayed good thermal stability,water resistance and long-acting antibacterial activity.
出处
《长春理工大学学报（自然科学版）》
2011年第2期169-172,共4页
Journal of Changchun University of Science and Technology(Natural Science Edition)
基金
国家自然科学基金项(20871058
20971028
21006038)
省部(院)产学研合作项目(2008A010500005
2010B090301036)
广东省自然科学基金重点项目(10251007002000000)
花都区产学研项目(HD10CXY-G004)
关键词
柱撑层状α-磷酸锆
季铵盐
热稳定性
耐水性
长效抗菌性能
pillared layered α-Zirconium phosphate
quaternary ammonium salts
water resistance
thermal stability
long-acting antibacterial activity
