2-羟基-4-仲辛基-二苯甲酮肟与P_(538)对钯的协同萃取

Synergistic Extraction of Palladium(Ⅱ) with P_(538 ) and 2-hydroxyl-4-sec n octyl diphenyloxime

确定了２羟基４仲辛基二苯甲酮肟（Ｎ５３０） 与Ｐ５３８ 对钯协同萃取的萃合物组成为：Ｌ·Ｐｄ·Ａ。协萃反应平衡常数为１ｇ Ｋ１２ ＝ ３ ．０５２ ，协同萃取配合物生成常数为β１２ ＝ ４３ ．１５ 。同时计算了部分协萃反应的热力学函数值。

The compsition of the synergistic extracting complexes with 2 hydroxyl 4 sec n octyl diphenyloxime (N 530 ) and P 538 have have been determined to be L·Pd·A.Moreover,the equilibrium constant,the forming constant and partly the thermodynamic functions of the synergistic reactions calculated.