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铁络合物催化类Fenton氧化研究进展

Progress in the research on iron complex catalyzed Fenton-like oxidation
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摘要 综述了铁络合物催化类Fenton氧化的研究进展。铁络合物与铁相比具有更高的催化活性,可提高水中有机物的去除效果。均相类Fenton存在后续金属离子的去除问题,因此铁络合物作为催化剂的多相催化类Fenton氧化具有更好的应用前景。重点介绍了高分子负载铁络合物催化类Fenton氧化降解水中有机物的研究现状及铁络合物催化类Fenton氧化的反应活性物种。 The progress in iron complex catalyzed Fenton-like oxidation is reviewed. Compared with iron, the iron complex has a higher catalytic activity to improve the removal rate of organic matter from water. The homogeneous Fenton-like catalyzed by iron complex may bring a problem of removing metallic ions in subsequent process, so the heterogeneous Fenton-like catalyzed by iron complex has a better future. The current research situation of the Fenton-like catalyzed by iron complex loaded on resin is introduced emphatically and the reactive species in the Fenton-like catalyzed by iron complex is discussed.
出处 《工业水处理》 CAS CSCD 北大核心 2011年第7期1-6,共6页 Industrial Water Treatment
基金 国家自然科学基金项目(50978067) 国家科技支撑计划项目(2006BAJ08B02 2006BAJ08B05) "十一五"水专项(2008ZX07421-002 2009ZX07424-005 2009ZX07424-006) 东北电力大学博士科研启动基金项目(BSJXM-200904)
关键词 铁络合物 类FENTON 卟啉 铁酞菁 多相类Fenton 高价态铁 iron complex Fenton-like porphyrin iron phthalocyanine heterogeneous Fenton-like ferryl
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