期刊文献+

铁络合物催化类Fenton氧化研究进展

Progress in the research on iron complex catalyzed Fenton-like oxidation
下载PDF
导出
摘要 综述了铁络合物催化类Fenton氧化的研究进展。铁络合物与铁相比具有更高的催化活性,可提高水中有机物的去除效果。均相类Fenton存在后续金属离子的去除问题,因此铁络合物作为催化剂的多相催化类Fenton氧化具有更好的应用前景。重点介绍了高分子负载铁络合物催化类Fenton氧化降解水中有机物的研究现状及铁络合物催化类Fenton氧化的反应活性物种。 The progress in iron complex catalyzed Fenton-like oxidation is reviewed. Compared with iron, the iron complex has a higher catalytic activity to improve the removal rate of organic matter from water. The homogeneous Fenton-like catalyzed by iron complex may bring a problem of removing metallic ions in subsequent process, so the heterogeneous Fenton-like catalyzed by iron complex has a better future. The current research situation of the Fenton-like catalyzed by iron complex loaded on resin is introduced emphatically and the reactive species in the Fenton-like catalyzed by iron complex is discussed.
出处 《工业水处理》 CAS CSCD 北大核心 2011年第7期1-6,共6页 Industrial Water Treatment
基金 国家自然科学基金项目(50978067) 国家科技支撑计划项目(2006BAJ08B02 2006BAJ08B05) "十一五"水专项(2008ZX07421-002 2009ZX07424-005 2009ZX07424-006) 东北电力大学博士科研启动基金项目(BSJXM-200904)
关键词 铁络合物 类FENTON 卟啉 铁酞菁 多相类Fenton 高价态铁 iron complex Fenton-like porphyrin iron phthalocyanine heterogeneous Fenton-like ferryl
  • 相关文献

参考文献52

  • 1Huang C P,Dong C ,Tang Z. Advanced chemical oxidation :its present role and potential future in hazardous waste treatment [J]. Waste Manage, 1993,13(5/6/7) :361-377.
  • 2Rahhal S, Richter H W. Reduction of hydrogen peroxide by the ferrous ion chelate of diethylenetriamine-N,N,N' ,N",N" -pentaacetate[J]. J. Am. Chem. Soc., 1988,110:3126-3133.
  • 3Rush J D, Koppenol W H. Oxidizing intermediates in the reaction of ferrous EDTA with hydrogen peroxide [J]. J. Boil. Chem., 1986, 261 (15) :6730-6733.
  • 4Watts R J ,Dilly S E. Evaluation of iron catalysts for the Fenton-like remediation of diesel contaminated soils[J]. J. Hazard. Mater., 1996,51 ( 1 ) : 209-224.
  • 5Zepp R G, Faust B C, Hoign J. Hydroxyl radical formation in aqueous reactions (pH: 3-8 ) of iron ( Ⅱ ) with hydrogen peroxide : the photo-Fenton reaction [ J ]. Environ. Sci. Technol., 1992,26 (2) : 313-319.
  • 6Malik P K. Oxidation of safranine T in aqueous solution using Fenton's reagent : Involvement of a Fe ( Ⅲ ) chelate in the catalytic hy- drogen peroxide oxidation of safranine T[J]. J. Phys. Chem. A, 2004,108(14) :2675-2681.
  • 7Fukushima M,Tatsumi K,Morimoto K. The fate of aniline after a photo-Fentan reaction in an aqueous system containing iron ( Ⅲ ), humic acid,and hydrogen peroxide[J]. Environ. Sci. Teehnol., 2000,34(10):2006-2013.
  • 8Fukushima M ,Sawada A,Kawasaki M ,et al. Influence of humic substances on the removal of pentachlorophenol by a biomimetic catalytic system with a water-soluble iron ( Ⅲ)-porphyrin complex [J]. Environ. Sci. Technol. ,2003,37(5) : 1031-1036.
  • 9Fukushima M ,Tatsumi K. Effect of hydroxypropyl-β-cyclo-dextrin on the degradation of pentachlorophenol by potassium monopersul- fate catalyzed with Iron ( Ⅲ)-porphyrin complex [J~. Environ. Sci. Technol., 2005,39 (23) : 9337-9342.
  • 10Paciolla M D, Davies G, Jansen S A. Generation of hydroxyl radi- cals from metal-loaded humic acids [J]. Environ. Sci. Teehnol.,1999, 33(11):1814-1818.

二级参考文献95

  • 1高冠道,陈金龙,费正皓,李爱民,鲁俊东,龙超,张全兴.超高交联树脂催化剂对水溶液中孔雀绿的催化降解研究[J].高分子学报,2006,16(1):113-117. 被引量:24
  • 2Ben A R, Liu M G, Vigneswaran S. Water Science and Technology, 1993,27 (10) : 141 - 149.
  • 3Bolton J R. Solar Detoxification, Solar Energy, 1996,56 (5):375.
  • 4Alexander M. Science,1981,211:132 - 134.
  • 5Meunier B. Chem Rev, 1992,92:1411 - 1456.
  • 6Sorokin A, Meunier B. Chem Commun, 1994,1799-1780.
  • 7Sorokin A, Seris J L, Meunier B. Science, 1995,268 : 1163 - 1166.
  • 8Tao X, Ma W, Zhang T, Zhao J. Angew Chem Int Ed, 2001,113:3013.
  • 9Cheng M M,Ma W H,Li J,Huang Y P,Zhao J C.Environ Sci Technol,2004,38:1569 - 1575.
  • 10Cheng M, Ma W, Li J, et al. 2004. Visible light assisted degradation of dye pollutants over Fe(Ⅲ)-Loaded Resin in the presence of H2O2 at neutral pH values [J]. Environmental Science & Technology, 38:1569-1575.

共引文献56

相关作者

内容加载中请稍等...

相关机构

内容加载中请稍等...

相关主题

内容加载中请稍等...

浏览历史

内容加载中请稍等...
;
使用帮助 返回顶部