期刊文献+

甲基橙掺杂聚吡咯纳米管的合成及其性能 被引量:4

Synthesis and performance of polypyrrole nanotubes doped with methyl orange
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摘要 通过化学氧化法,以Fe(NO3)3为氧化剂,甲基橙(MO)为掺杂剂合成了聚吡咯纳米空心管.通过FT-IR、SEM、TEM和电导率测试等研究了氧化剂和掺杂剂等对聚吡咯形貌结构和电导率的影响;并将聚吡咯纳米管涂覆在工作电极表面制作而成的修饰电极经循环伏安法测试表明具有良好的氧化还原可逆性. Polypyrrole nanotubes are one kind of the most promising materials for potential applications.In this paper,polypyrrole nanotubes doped with methyl orange(MO) were prepared by using Fe(NO3)3 as the oxidant.The effects of Fe(NO3)3 and MO on the morphology and conductivity of the nanotubes have been studied by FT-IR,SEM,TEM and conductivity test.Moreover,the cyclic voltammetry indicated that the polypyrrole nanotubes modified electrode possessed the redox reversibility.
出处 《武汉工程大学学报》 CAS 2011年第7期17-21,共5页 Journal of Wuhan Institute of Technology
关键词 导电聚合物 聚吡咯纳米管 氧化剂 掺杂剂 修饰电极 polypyrrole nanotubes methyl orange modified electrode
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参考文献14

  • 1Yang X M, Zhu Z X, Dai T Y, et al. Facile fabrication of functional polypyrrole nanotubes via a reactive self - degraded template [J ]. Macromol Rapid Commun, 2005, 26: 1736- 1740.
  • 2Gao H X, Jiang T, Han B X, et al. Aqueous/ionic liquid interfaeial polymerization for preparing polyaniline nanoparticles [J]. Polymer, 2004, 45 (9):3017.
  • 3吕进玉,林志东,曾文.RuO_2/聚苯胺复合材料电极的制备及电化学性能表征[J].武汉工程大学学报,2008,30(1):62-65. 被引量:6
  • 4Zhang L J, Wan M X. Self- assembly of polyaniline from nanotubes to hollow microspheres [J]. Advanced Functional Materials, 2003, 13 (10) : 815.
  • 5Qiu H J, Zhai J, Li S H, et al. Oriented growth of self- assembled polyaniline nanowire arrays using a novel metod [J]. Advanced Functional Materials, 2003, 13(12): 925.
  • 6Pillalamarri S K, Blum F D, Tokuhiro A T, et al. Radiolytic synthesis of polyaniline nanofibers: a new templateless pathway [J]. Chem Mater, 2005, 17: 227.
  • 7Chung C K. The bromine doping of polyacetylene [J]. Plays, 2003, 321(1/2): 139.
  • 8Liu Y C, Chung K C. Characteristics of conductivity -improved polypyrrole films via different procedures[J]. Synthtie Metals, 200a, la9(2): 277.
  • 9Udum Y A, Pekmez K Y, Electropolymerization of self- doped polythiophene in acetonitrile containing FSO3H [J]. Synthetic Metals, 2004, 142(1/2/3) : 7.
  • 10Xing S X, Zhao C, Jin S Y, et al. Morphology and conductivity of polyaniline nanofibers prepared by seeding polymerization [-J]. Polymer, 2006, 47: 2305.

二级参考文献14

共引文献13

同被引文献33

  • 1卢小琳,国伟林,王西奎.超声化学法制备无机纳米材料的研究进展[J].中国粉体技术,2004,10(1):44-48. 被引量:23
  • 2王家芳,章文贡.溶胶-凝胶法合成有机无机杂化材料进展——2组分间以次价力作用的有机无机杂化材料[J].高分子通报,2001(2):30-36. 被引量:17
  • 3李永舫.导电聚合物的电化学性质[J].复旦学报(自然科学版),2004,43(4):468-476. 被引量:33
  • 4李永舫.导电聚吡咯的研究[J].高分子通报,2005(4):51-57. 被引量:52
  • 5Qian R Y,Pei Q B,Huang Z T. The role of H^+ ions in the electrochemical polymerization of pyrrole in aqueous media [J].Makeromol Chem, 1991, 192:1263.
  • 6Lakshinandan Goswami,Neelotpal Sen Sarma, Deva- sish Chowdhury. Bias-Induced Enhancement of Cond- uctivity in Polypyrrole[J]. The Journal of Physical Chemistry, 2012,116 : 6446-6452.
  • 7Junyu Lei, Xiaofeng Lu, Wei Wang, et al, Fabrication of MnO2/graphene oxide composite nanosheets and their application in hydrazine detection[J].The Royal Society of Chemistry, 2012,2:2541-2544.
  • 8Jianfeng Zang, Xiaodong Li. In situ synthesis of ultrafine β-MnO2/polypyrrole nanorod composites for high-performance supercapacitors[J]. Journal of Materials Chemistry,2011,21,10965-10969.
  • 9Ferreira J,Santos M J, Matos R, et al. Structural and electrochromic study of polypyrrole synthesized with azo and anthraquinone dyes [J]. Journal of Electroanal Chemistry, 2006,591(1) : 27-32.
  • 10Girotto E M,Gazotti W A,Tormena C F,et al. Pho- toelectronic and transport properties of polypyrrole doped with a dianionie dye[J]. Electroehimiea Acta, 2002, 47(9) :1351-1357.

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