前端聚合在聚合物材料中的研究进展

Progress of frontal polymerization in polymer materials

前端聚合是一种通过局部反应区域在聚合物单体中的移动而将聚合物单体转变为聚合物的一种新型自由基反应模式,具有反应条件温和、速度快且节能的特点。本文阐述了前端聚合的反应原理、特点及在合成共聚物、水凝胶、互穿网络、复合材料等方面的应用。

Frontal polymerization is a new radical polymerization mode,which involves the conversion of monomer to polymer in a localized reaction zone.It has many characters such as mild reaction condition,rapid reaction and low energy consumption.Reaction principle,characters,and the application of frontal polymerization in synthesizing copolymer,hydrogels,interpenetrating networks,uniform composites were explored.