高温水泥浆降失水剂DRF-120L的制备及评价

Preparation and evaluation of high temperature cement slurry loss reduction additive DRF-120L

目前国内使用的合成聚合物类降失水剂普遍存在抗高温、抗盐能力差的问题,为解决这一问题,从分子结构入手,优选出性能优异的聚合单体,采用水溶液自由基共聚合法制备了抗高温、抗盐降失水剂DRF-120L。DRF-120L分子主链上引入了磺酸基及双羧基等多种官能团,提高了降失水剂对水泥粒子的吸附能力,从而提高了降失水剂在高温下控制水泥浆失水的能力。分别考察了引发剂加量、反应温度及单体浓度等因素对降失水剂性能的影响,确定了聚合反应的最佳合成条件,制备出了抗温达到200℃的降失水剂DRF-120L。DRF-120L在高温下能将淡水水泥浆及含盐水水泥浆API失水量控制在100mL以内且对水泥石的强度发展无不良影响;以DRF-120L为主剂的常规密度水泥浆及高密度水泥浆均具有良好的综合性能,能够满足高温深井固井的需要。

The cement fluid loss reduction additives used in China generally have the deficiency of weak salinity tolerance and poor thermal stability.To solve this problem,considering molecular structure,excellent performance monomers were selected,and then the salt tolerant and thermostable fluid loss reduction additive DRF-120L was prepared according to free radical polymerization in aqueous solution.DRF-120L is a type of copolymer and its main chain contains sulfonic group and dicarboxyl groups,which improves the adsorption capacity to cement particle,so the capacity of controlling fluid loss was improved.The initiator amount,reaction temperature,monomer mass fraction were investigate,and the optimum polymerization conditions was determined.Finally DRF-120L was synthesized with temperature resistance of up to 200 ℃.API fluid loss both in fresh water cement slurry and saline water cement slurry can be controlled under 100 ml under high temperature.DRF-120L has little effect on development ofcement strength under high temperature.Both conventional density cement slurry and high density cement slurry mixed mainly with DRF-120L have good comprehensive properties.Therefore,DRF-120L can satisfy the requirement of high temperature and deep well cementing.