摘要
合成了[Co(C5O2H8)2].H3COH金属配合物,通过X射线衍射仪测得配合物[Co(C5O2H8)2].H3COH的晶体结构。晶体属于单斜晶系,空间群为P 2(1)/c。其晶胞参数为a=0.93325(16)nm,b=1.15015(16)nm,c=1.30029(16)nm,α=90.00°,γ=90.00°,β=92.9680(10)°,V=1.3938(4)nm3,Z=4,D c=1.388g.cm-3,F(000)=612;最终偏差因子R1=0.0581,wR2=0.1700和R1=0.0676,wR2=0.1786。
A novel complex[Co(C5O2H8)2]·H3COH was synthesized,the crystal structure of which was analyzed by X-ray diffraction.The crystal is monoclinic crystal with space group of P2(1)/c,and cell parameters are follow:a=0.93325(16)nm,b=1.15015(16)nm,c=1.30029(16)nm,α=90.00°,γ=90.00°,β=92.9680(10)°,V=1.3938(4)nm3,Z=4,Dc=1.388g·cm-3,F(000)=612;R1=0.0581,wR2=0.1700 and R1=0.0676,wR2=0.1786.
出处
《光谱实验室》
CAS
CSCD
北大核心
2011年第4期1926-1929,共4页
Chinese Journal of Spectroscopy Laboratory
基金
生物传感与疾病检测系统研究平台(广西科学研究与技术开发计划课题
2009B02)
关键词
钴
配合物
晶体结构
Cobal
Complex
Crystal Structure