[Co(C_5O_2H_8)_2]·H_3COH的水热合成和晶体结构

Hydrothermal Synthesis and Crystal Structure of [Co(C_5O_2H_8)_2]·H_3COH

合成了[Co(C5O2H8)2].H3COH金属配合物,通过X射线衍射仪测得配合物[Co(C5O2H8)2].H3COH的晶体结构。晶体属于单斜晶系,空间群为P 2(1)/c。其晶胞参数为a=0.93325(16)nm,b=1.15015(16)nm,c=1.30029(16)nm,α=90.00°,γ=90.00°,β=92.9680(10)°,V=1.3938(4)nm3,Z=4,D c=1.388g.cm-3,F(000)=612;最终偏差因子R1=0.0581,wR2=0.1700和R1=0.0676,wR2=0.1786。

A novel complex[Co（C5O2H8）2]·H3COH was synthesized,the crystal structure of which was analyzed by X-ray diffraction.The crystal is monoclinic crystal with space group of P2（1）/c,and cell parameters are follow：a=0.93325（16）nm,b=1.15015（16）nm,c=1.30029（16）nm,α=90.00°,γ=90.00°,β=92.9680（10）°,V=1.3938（4）nm3,Z=4,Dc=1.388g·cm-3,F（000）=612;R1=0.0581,wR2=0.1700 and R1=0.0676,wR2=0.1786.