期刊文献+
任意字段
题名或关键词
题名
关键词
文摘
作者
第一作者
机构
刊名
分类号
参考文献
作者简介
基金资助
栏目信息

Suzuki偶联反应中钯配合物催化剂的研究进展 被引量：5

Research Progress in Palladium Ligand Catalysts on Suzuki Coupling Reaction
原文传递
导出
摘要 Suzuki偶联反应是在零价钯配合物催化剂的催化下,芳基硼酸与卤代芳烃进行的交叉偶联反应,可以高效、高选择性地构建C-C键。钯配合物催化剂对Suzuki偶联反应的活性和选择性起着决定性的影响,是研究Suzuki偶联反应的关键。对含有膦配体、N-卡宾配体、亚胺配体、胺配体和其它配体的钯配合物催化剂催化效果进行了综述。 Suzuki coupling reactions are a kind of reactions between organic arylboronic acid and aryl halides to construct C-C bond over the ze- ro-valent palladium catalysts with high efficiency and selectivity. Palladium ligand catalysts, which are the key of study on Suzuki coupling reaction, play an important role in the activity of Suzuki coupling reaction. The catalytic properties of phosphine ligand, N-hetcroeyclic carbine ligand, imine ligand, amine ligand and other ligands of palladium complex are summarized.
作者 李瑞 白雪峰
机构地区 黑龙江省科学院石油化学研究院
出处 《化学与粘合》 CAS 2011年第4期55-59,共5页 Chemistry and Adhesion
关键词 SUZUKI偶联反应 钯配合物 研究进展 Suzuki coupling reaction palladium ligands research progress
分类号 TQ426.8 [化学工程]
  • 相关文献

参考文献29

  • 1MIYAUR N, YANAI T, SUZUKI A.The palladi urn-catalyzed cross-coupling reaction of phenylboronic acid with haloarenes in the presence of base [J].Synthetic Communications,1981,11 (7): 513-515.
  • 2SUZUKI A.Recent advances in the cross-coupling reactions of organoboron derivatives with organic eIectrophiles,1995-1998 [J].Joumal of Organometallic Chemistry,1999,576:147~168.
  • 3CAVE G W V, LYDON D P, ROURKE J P.Cyclopalladatedschiff's base liquid crystals: the effect of the acac group on the thermal behavior[J].Journal of Organometallic Chemistry,1998, 555:81~88.
  • 4GREEN M L H, MARDER S R, THOMPSON M E, et al.Synthe- sis and structure of (cis)-[ 1-ferrocenyl-2-(4-nitrophenyl)ethy- lene], an organotransition metal compound with a large second- order optical nonlinearity [ J ].Nature, 1987,330(6146):360~362.
  • 5ALEXANDER Z F, RALF J, MATI'HISA B, et al.Practical syn- thesis of new and highly efficient ligands for the Suzuki reaction of aryl chlorides[J].Chemical Communications,2004,1:38-39.
  • 6BUCHWALD S L, BARDER T E, WALKER S D, et al.Catalysts for Suzuki-Miyaura coupling processes: scope and studies of the effect of ligand structure[J].Journal of the American Chemical Society,2005,127:4685~4696.
  • 7FEUERSTEIN M,LAURENTI D, BOUGEANT C, et al.Palladium tetraphosphine catalysed cross coupling of aryl bromides with arylboronic acids:remarkable influence of the nature of the ligand [ J ].Chemical Communications,2001,325N326.
  • 8FEUERSTEIN M, DOUCET H, STANTELLI M.Tetraphosphine/ palladium-catalysed Suzuki cross-coupling with sterically hin- dered aryl bromides and arylboronic acids [J].Tetrahedron Let- ters,2001,42:6667~6670.
  • 9FEUERSTEIN M, DOUCET H, STANTELLI M.Efficient coupling of heteroaryl bromides with arylboronic acids in the presence of a palladium tetraphosphine catalyst [J].Tetrahedron Letters,2001, 42:5659~5662.
  • 10FEUERSTEIN M, DOUCET H, SANTELLI M.Palladium eataly sed cross-coupling of aryl chlorides with arylboronic acids in the presence of a newtetraphosphine ligand[J].Synlett,2001, 1458.

同被引文献27

引证文献5

二级引证文献5

化学与粘合
2011年 第4期

相关作者

内容加载中请稍等...

相关机构

内容加载中请稍等...

相关主题

内容加载中请稍等...

浏览历史

内容加载中请稍等...
;
使用帮助 返回顶部