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Microwave promoted rapid dehydration of aldoximes to nitriles using melamine-formaldehyde resin supported sulphuric acid in dry media 被引量:6

Microwave promoted rapid dehydration of aldoximes to nitriles using melamine-formaldehyde resin supported sulphuric acid in dry media
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摘要 为由用在没有溶剂的状况下面的三聚氰胺甲醛树脂(MFR ) 上的支持的硫的酸的 aldoxime 的脱水的 nitriles 的合成的一个简单、方便的过程被开发了。许多芳香、脂肪族的 aldoximes 被变换成相应 nitriles。树脂为随后的反应被恢复并且再使用。 A simple and convenient procedure for the synthesis of nitriles by dehydration of aldoxime using supported sulphuric acid on melamine-formaldehyde resin (MFR) under solvent-free condition has been developed. A variety of aromatic and aliphatic aldoximes were converted to the corresponding nitriles. The resin was recovered and reused for subsequent reactions. ~ 2011 Ramin Rezaei. Published by Elsevier B.V. on behalf of Chinese Chemical Society. All rights reserved.
出处 《Chinese Chemical Letters》 SCIE CAS CSCD 2011年第7期815-818,共4页 中国化学快报(英文版)
关键词 三聚氰胺甲醛树脂 微波促进 干燥介质 脱水 硫酸 无溶剂条件 中国化学会 Aldoximes Nitriles Melamine-formaldehyde resin Sulphuric acid Solvent-free
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