摘要
为由用在没有溶剂的状况下面的三聚氰胺甲醛树脂(MFR ) 上的支持的硫的酸的 aldoxime 的脱水的 nitriles 的合成的一个简单、方便的过程被开发了。许多芳香、脂肪族的 aldoximes 被变换成相应 nitriles。树脂为随后的反应被恢复并且再使用。
A simple and convenient procedure for the synthesis of nitriles by dehydration of aldoxime using supported sulphuric acid on melamine-formaldehyde resin (MFR) under solvent-free condition has been developed. A variety of aromatic and aliphatic aldoximes were converted to the corresponding nitriles. The resin was recovered and reused for subsequent reactions. ~ 2011 Ramin Rezaei. Published by Elsevier B.V. on behalf of Chinese Chemical Society. All rights reserved.