摘要
以稻壳为原料,通过流化床快速热解的方式制备生物油。初步考察了螺旋进料速率对流化床反应参数的影响。当进料速率由4kg/h提高至5kg/h时,床层温度明显下降,床层压差明显增加,燃气流量也明显增加,表明热解产物更多地发生了二次裂解反应。采用GC-MS对快速热解所得生物油的组成进行分析,采用TG—DSC考察生物油的热稳定性,表明在250—400℃之间,出现较强的放热现象,缩聚现象严重,并对其重要的燃料性能进行表征,pH值2.33,水分24.0%,热值16.3MJ/kg,密度1.17g/mL,黏度45mm2/s(30℃)。
Bio-oil from rice husk was prepared by fast pyrolysis. The effect of feed rate on the reaction parameters of fluidized reactor was investigated. With increasing feed rate (4 kg/h to 5 kg/h) it was found that the pressure difference and pyrolysis gas were also increased, while reaction temperature decreased. These results indicated that secondly-cracking reaction was increased in pyrolytic products. The components of product were analysized by GC-MS. Thermal stability of bio-oil was determined by TG-DSC. The major fuel properties of bio-oil were characterized.
出处
《生物质化学工程》
CAS
2011年第4期23-26,共4页
Biomass Chemical Engineering
基金
国家林业局公益性行业专项(200904008)
关键词
稻壳
热解
生物油
rice husk
pyrolysis
bio-oil