摘要
合成了[二(2-苯并咪唑亚甲基)胺][咪唑]合Cu(Ⅱ)Zn(Ⅱ)Cu(Ⅱ)高氯酸盐配合物C_(57)H_(57)N_(21)Cu_2Zn(ClO_4)_6·6[(CH_3)_2NCHO],并进行了元素分析、红外和紫外表征,用X射线衍射的方法测定了晶体结构。
A novel trinuclear complex, bis (μ-perchlorato ) tri [ N, N-bis ( benzimidazol-2-ylmethyl) amine]dicopper (Ⅱ) zinc(Ⅱ) perchloroate, C57 H57 N21 Cu2Zn ( ClO4 )6·6 [ ( CH3 )2NCHO ] was synthesized and characterized with element analysis, UV, and IR spectra. The crystal structure was determined by X-ray diffraction. The biological activities were measured and quantum chemistry computation was carried out.
出处
《化学学报》
SCIE
CAS
CSCD
北大核心
1999年第11期1185-1192,共8页
Acta Chimica Sinica
基金
天津市教委重点学科资助项目
关键词
SOD
模型物
苯并咪唑亚甲基
胺三核配合物
synthesis
crystal structure
trinuclear complex of N
N-bis ( benzimidazol-2-ylmethyl) amine
quantum chemistry calculation
