期刊文献+

含氟弹性体对聚烯烃挤出性能的改善 被引量:5

IMPROVEMENT OF THE POLYOLEFIN EXTRUSION PROPERTIES BY FLUOROCARBON ELASTOMER ADDITIVE
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摘要 熔体破裂是挤出成型中遇到的最严重的问题。在树脂中掺入适量的含氟弹性体,是减轻甚至消除熔体破裂的有效措施。PPA2231及FKM-A是较有代表性的两种含氟弹性体。本文介绍了物料制备及实验的方法,利用毛细管流变仪的大量实验结果,详尽分析了这两种含氟弹性体对LLDPE、HDPE及PP这三种聚烯烃树脂挤出性能的效应。并简述了在挤出加工时,含氟弹性体还可降低熔体温度,减小机头压力,提高挤出效率。 Melt breakage is the most serious problem met in the plastics extruding moulding. Blending certain quantity of florine containing elas-tomer additive into resin is an effective measure to lighten or even eliminate melt breakage. PPA 2231 and FKM-A are two typical florine containing elastomers. This paper describes the preparation of these materials and the experiment method.Based on results of experiment using capillary rheometer, the effects of these two florine containing elastomers on the extruding pro- perties of LLDPE, HDPE and PP resins are analysed in detail. Florine containing elastomer can also decrease the melt temperature ~f the resin and decrease the pressure on the machine head and increase the extrusion efficiency.
作者 黄汉雄
机构地区 华南理工大学
出处 《现代塑料加工应用》 CAS 1990年第1期15-23,共9页 Modern Plastics Processing and Applications
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  • 1华幼卿,斯钦达来,金日光.增塑高分子量PVC树脂的流变性能研究[J].塑料工业,1994,22(4):20-24. 被引量:4
  • 2黄汉雄.几种消除熔体破裂的方法[J].高分子材料科学与工程,1990,6(1):11-18. 被引量:7
  • 3王十庆.海外科学高分子科学的新进展[M].北京:化学工业出版社,1997.217-231.
  • 4Rudin.A Use of Fluorocarbon Elastomers as Processing Additives for Polyolefins [J].Polym.Plast.Technol.Eng,1990,29(3):199~234
  • 5Rudin A. Use of fluorocarbon elastomers as processing additives for polyolefins. Polym Plast Technol Eng, 1990 ,29(3) :199-234
  • 6Jia Chunfeng. Assessment of efficacy of trivalent lanhtanum complex as surface modifier of calcium carbonate. Journal of Applied Polymer Science ,2001,82(6):1 339-1 345
  • 7王十庆.毛细管流动中的聚合物熔体分子不稳定性-界面黏滑转变壁滑及挤出物畸变[M]//何天白,胡汉杰.海外高分子科学的新进展,北京:化学工业出版社,1997:217-232.
  • 8COGSWELL F N. Stretching flow instabilities at the exits of extrusion dies[J]. J Non-Newtonian Fluid Mech, 1977, (2): 37- 47.
  • 9REGIS J, JEAN-JACQUES L, JOACHIM M. Composition including a fiuoroelastomer and a thermoplastic polyamide and resulting film: US, 5986005 [P]. 1999 - 11 - 17.
  • 10JARVENKYLA J, LAHTINEN T. Method and apparatus for making an extrusion product, and an extrusion product: US, 6203651 [P]. 2001-03-20.

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