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CeO_2/O_3催化氧化对滤后水中小分子副产物生成的影响 被引量:1

Effect of Catalytic Ozonation with Supported Cerium Oxide on the Formation of Low Molecular Weight Oxidation By-Products of Filtered Surface Water
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摘要 考察了连续流体系中,滤后水经氧化铈催化臭氧氧化(CeO2/O3)后小分子醛、酮、羧酸及酮酸副产物的生成情况.发现CeO2/O3明显提高了DOC和SUVA的去除率,醛、酮副产物的产量比单独O3氧化后的增加了8%,而羧酸和酮酸的产量却比单独O3氧化后的分别降低了28%和54%.羧基类副产物大幅降低的原因主要与CeO2表面Ce(Ⅳ)对羧基官能团较强的络合亲合力有关.CeO2/O3氧化后小分子副产物总量比单独O3氧化后的降低了23%,但用小分子副产物总量折算有机碳占DOC的比例来间接显示氧化后剩余DOC的可生物降解性,结果表明,CeO2/O3进一步提高了滤后水剩余DOC的可生化性. The aim of the work is to investigate the formation of the low molecular weight(LMW)oxidation by-products(i.e.aldehydes,ketones,carboxylic acids and ketoacids)after cerium oxide-catalyzed ozonation(CeO2/ O3)of filtered waters in a continuous flow reactor.Results showed that CeO2/O3 can evidently improve the reduction of the dissolved organic matter(DOC)and specific UV absorbance(SUVA).Compared with ozonation alone,CeO2/O3 caused an increment of the formation of aldehydes and ketones by about 8%,and a significant reduction of the formation of carboxylic acids and ketoacids by 28% and 54%,respectively.The great reduction of carboxyl group by-products is mainly attributed to the high affinity of Ce(Ⅳ)to the carboxyl group on the surface of CeO2 during CeO2/O3 oxidation.The total production of LMW by-products reduced by 23%.However,the filtered water became more biodegradable after catalytic ozonation,because the percentage of total LMW by-products carbon in the final DOC after catalytic ozonation was higher than that after ozonation alone.
出处 《天津大学学报》 EI CAS CSCD 北大核心 2011年第7期597-601,共5页 Journal of Tianjin University(Science and Technology)
基金 国家自然科学基金资助项目(51008162) 天津市应用基础及前沿技术研究计划资助项目(10JCYBJC03500) 南开大学青年教师及海外留学归国人员资助项目(65010371)
关键词 氧化铈 催化臭氧氧化 羧酸 连续流 cerium oxide catalytic ozonation aldehyde ketone carboxylic acid continuous flow
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参考文献15

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