摘要
合成了新的离子液体金属配合物[Pb(m-HNA)(H2O)].NO3.3H2O(m-HNA为N,N′-二-羧甲基-2-丙基苯并咪唑盐),并通过元素分析,红外光谱,对其进行了表征,通过X射线单晶衍射测定了其晶体结构,在晶体结构中,标题物通过π-π相互作用、分子间氢键和配位键自组装成了三维网状结构。另外,电化学性质表明,该配合物的电解过程为准可逆过程。
One new ionic liquids metal coordination polymer [Pb（m-HNA）（H 2 O）]·NO 3 ·3H 2 O has been synthesized and characterized by IR,and elemental analysis.The single crystal structures of the title compound is determined by X-ray diffraction.In crystal,the title compound self-assembled to three-dimensional structure by π-π interaction,hydrogen and coordination bonding.In addition,the results of the electrochemical properties show the compound exhibits a quasi-reversible electrode process.
出处
《无机化学学报》
SCIE
CAS
CSCD
北大核心
2011年第8期1569-1573,共5页
Chinese Journal of Inorganic Chemistry
基金
国家自然科学基金(No.20671077)资助项目
关键词
离子液体
配位聚合物
Π-Π相互作用
电化学性质
ionic liquids
coordination polymer
π-π interaction
electrochemical properties
