温和条件下羰基合成的新方法

NOVEL METHODS FOR CARBONYLATION UNDER AMBIEBT CONDITIONS

介绍了以烯烃、卤代烃、烷烃及芳烃为底物 ,在光促进和温和条件下 ,用过渡金属催化进行羰基合成的新方法。试验结果表明 ,上述底物用这种新方法进行羰基合成 ,反应的选择性好 ,其中烯烃和卤代烃的收率也较高。可以预计这种新的羰基合成方法的研究具有一定的理论和应用价值。

Novel methods for the carbonylation are introduced of olefins,halides,paraffins,and arenes under ambient conditions and UV irradiation catalyzed by transition metal complexes.The results have shown that the selectivities are good for all substrates and the yields are satisfactory for olefins and halides in this way.It is expected that the methods would be promising as applied as new carbonylation technique.