期刊文献+

HF酸电解液浓度对TiO_2纳米阵列结构的影响 被引量:1

Influence of HF Electrolyte Concentration on TiO_2 Ordered Arrays
下载PDF
导出
摘要 TiO2纳米阵列(纳米管、纳米棒)结构具有良好的力学性能、化学稳定性以及抗腐蚀性能,在许多技术领域具有广阔的应用前景。采用阳极氧化法在工业纯钛片表面制备出高度有序的TiO2纳米管阵列和纳米棒阵列,研究了电解液浓度和阳极氧化时间对TiO2纳米阵列结构的影响,并对其形成机理进行了初步探讨。结果表明,低浓度的HF酸电解液有利于制备纳米管阵列,高浓度的HF酸电解液有利于制备纳米棒阵列。 TiO2 ordered arrays(nanotubes, nanorods) have attracted a great deal of attention in various fields due to their noticeable excellent properties. TiO2 ordered arrays were prepared by potentiostatic oxidization on the surface of the industrial pure titanium film, the influences of electrolyte concentration and oxidation time on TiO2 ordered arrays were studied, and the formation mechanism was preliminarily discussed. Results show that low hydrofluoric acid concentration helps to form nanotube arrays while high concentration helps to achieve the freestanding nanorod arrays.
出处 《材料导报》 EI CAS CSCD 北大核心 2011年第16期79-81,107,共4页 Materials Reports
基金 青岛科技大学博士启动基金
关键词 阳极氧化 电解液 纳米棒阵列 纳米管阵列 anodization, electrolyte, nanorod arrays, nanotube arrays
  • 相关文献

参考文献20

  • 1YANG LiXia,LUO ShengLian,CAI QingYun,YAO ShouZhuo.A review on TiO_2 nanotube arrays:Fabrication, properties, and sensing applications[J].Chinese Science Bulletin,2010,55(4):331-338. 被引量:11
  • 2Zhen Wei,Zheng Liu,Rongrong Jiang,Chaoqing Bian,Tao Huang,Aishui Yu.TiO2 nanotube array film prepared by anodization as anode material for lithium ion batteries[J]. Journal of Solid State Electrochemistry . 2010 (6)
  • 3Chien-Chon Chen,Wen C. Say,Sheng-Jen Hsieh,Eric Wei-Guang Diau.A mechanism for the formation of annealed compact oxide layers at the interface between anodic titania nanotube arrays and Ti foil[J]. Applied Physics A . 2009 (3)
  • 4Jing Bai,Baoxue Zhou,Longhai Li,Yanbiao Liu,Qing Zheng,Jiahui Shao,Xinyuan Zhu,Weimin Cai,Junsheng Liao,Lexi Zou.The formation mechanism of titania nanotube arrays in hydrofluoric acid electrolyte[J]. Journal of Materials Science . 2008 (6)
  • 5Kang T S,Smith A P,Taylor B E,et al.Fabrication ofhighly-ordered TiO2nanotube arrays and their use in dye-sensitized solar cells. Nano Letters . 2009
  • 6Roy P,Kim D,Paramasivam I,et al.Improved efficiencyof TiO2nanotubes in dye sensitized solar cells by decorationwith TiO2nanoparticles. Electrochemistry Communications . 2009
  • 7Lin C J,et al.Surface modification of highly ordered TiO2nanotube arrays for efficient photoelectrocatalytic watersplitting. Applied Physics Letters . 2009
  • 8Park J,Bauer S,Schlegel K A,et al.TiO2nanotube sur-faces:15nm-an optimal length scale of surface topographyfor cell adhesion and differentiation. Small . 2009
  • 9Allam N K,Grimes C A.Formation of vertically orientedTiO2nanotube arrays using a fluoride free HCl aqueous elec-trolyte. J Phys Chem C . 2007
  • 10Shankar K,Mor G K,Fitzgerald A.Cation effect on theelectrochemiacal formation of very high aspect ratio TiO2nanotube arrays in formamide-water mixtures. J PhysChem C . 2007

二级参考文献46

  • 1Paulose M, Shankar K, Yoriya S, et al. Anodic growth of highly-ordered TiO2 nanotube arrays to 134 μm in length. J Phys Chem B, 2006, 110: 16179-16184.
  • 2Sorachon Y, Maggie P, Varghese O K, et al. Fabrication of vertically oriented TiO2 nanotube arrays using dimethyl sulfoxide electrolytes. J Phys Chem C, 2007, 111 : 13770-13776.
  • 3Tsuchiya H, Macak J M, Taveira L, et al. Self-organized TiO2 nanotubes prepared in ammonium fluoride containing acetic acid electrolyres. Electrochem Commun, 2005, 7:576-580.
  • 4Prakasam H E, Shankar K, Paulose M, et al. A new benchmark fbr TiO2 nanotube array growth by anodization. J Phys Chem C, 2007, 111 : 7235-7241.
  • 5Park J H, Kim S, Bard A. Novel carbon-doped TiO2 nanotube arrays with high aspect ratios for efficient solar water splitting. Nano Lett, 2006, 6:24-28.
  • 6Vitiello R P, Macak J M, Ghicov A. N-doping of anodic TiO2 nanotubes using heat treatment in ammonia. Electrochem Commun, 2006, 8:544-548.
  • 7Ghicov A, Macak J M, Tsuchiyalon H, et al. Implantation and annealing for an efficient N-doping of TiO2 nanotubes. Nano Lett, 2006, 6:1080-1082.
  • 8Lu N, Quan X, Li J, et al. Fabrication of boron-doped TiO2 nanotube array electrode and investigation of its photoelectrochemical capability. J Phys Chem C, 2007, 111: 11836-11842.
  • 9Banerjee S, Mohapatra S K, Das P P, et al. Synthesis of coupled semiconductor by filling 1D TiO2 nanotubes with CdS. Chem Mater, 2008, 20:6784-6791.
  • 10Kongkanand A, Tvrdy K, Takechi K, et al. Quantum dot solar cells tuning photoresponse through size and shape control of CdSe-TiO2 architecture. J Am Chem Soc, 2008, 130:4007-4015.

共引文献10

同被引文献6

引证文献1

相关作者

内容加载中请稍等...

相关机构

内容加载中请稍等...

相关主题

内容加载中请稍等...

浏览历史

内容加载中请稍等...
;
使用帮助 返回顶部