摘要
5-羟甲基糠醛(HMF)是一种重要的平台化合物,具有广阔的应用前景。目前很多研究者已对如何提高HMF的产率和降低HMF的制备成本开展了多方面研究。本文综述了2006—2010年HMF的主要制备方法及研究特色,并对原料(单糖、多糖)、催化剂(固体酸、均相催化剂)、溶剂体系(单相体系、双相体系)及其它辅助条件(微波加热法、添加调节剂法)进行了系统总结与全面分析;同时,介绍了HMF的重要衍生物及其应用;最后指出了目前研究中存在的突出问题,并对其中的主要研究方向进行了归纳。
5-Hydroxymethylfurfural（HMF）is an important platform chemical with great application value.Enhancing the efficiency of synthesis and reducing the cost of production for HMF have been investigated by many researchers.Firstly,this paper introduced the generation mechanism of HMF.Based on the reaction scheme,many kinds of synthetic method of HMF from year 2006 to 2010 were summarized,and categorized as raw materials（monosaccharide and polysaccharides）,catalysts（solid acid catalysts and homogeneous acid catalysts）,reaction solvents（single-phase system and two-phase system）and subsidiary conditions（microwave-assisted heating and supplementary modifiers）.Meanwhile,the HMF derivatives and their applications is briefly introduced.Finally,prominent problems of current studies are discussed,and main research fields are also analyzed.
出处
《化工进展》
EI
CAS
CSCD
北大核心
2011年第9期1937-1945,共9页
Chemical Industry and Engineering Progress
基金
新世纪优秀人才支持计划(NCET-08-0386)
"111"引智项目(B06006)
关键词
5-羟甲基糠醛
生物质
原料
溶剂体系
催化剂
5-hydroxymethyl furfural
biomass
raw material
reaction solvent
catalyst
