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苯胺绿分子印迹聚合物制备条件对识别能力的影响 被引量：1

Effect of preparation conditions of aniline green molecular engram polymer to recognition
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摘要 本文研究了在以苯胺绿为模板分子,α-甲基丙烯酸(MMA)和2-乙烯基吡啶为功能单体,乙二醇二甲基丙烯酸酯(EGDMA)为交联剂,偶氮二异丁腈为引发剂,乙腈和四氢呋喃为溶剂分别在热引发和光引发的条件下合成以孔雀石绿为模板分子的印迹聚合物的实验过程中,通过选择不同配比的反应物,分析了各种合成条件对印迹聚合物识别能力的影响。 The molecular engram polymerof malachite green as template molecule was prepared with aniline green as template molecule,MMA and 2-vinylpyridine as photomonomer,EGDMA as crosslinking agent,azobisisobutyronitrile as initiator,methyl cyanide and butylene oxide as dissolvent,under the conditions of thermal initiation and photo-initiation.The effects of different conditions to recognition of molecular engram polymer were analyzed.
作者 何丹凤 王丽敏 初洪涛 苏连江 张永忠 侯近龙
机构地区 大庆师范学院化学化工学院黑龙江省普通高等学校油田应用化学重点建设实验室 齐齐哈尔大学化学与化学工程学院
出处 《化学工程师》 CAS 2011年第8期6-8,共3页 Chemical Engineer
基金 黑龙江省教育厅科学技术研究项目(11533002)
关键词 苯胺绿 分子印迹 引发方式 功能单体 交联剂 aniline green molecular engram initiation method photomonomer crosslinking agent
分类号 D635.6 [政治法律—中外政治制度]
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参考文献4

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同被引文献19

  • 1Aydogan S,Güllü.A study of the rectifying behaviour of aniline green-based Schottky diode[J].Microelectronic Engineering,2010,87(2):187-191.
  • 2Pourreza N,Elhami S.Spectrophtometric determination of malachite green in fish farming water samples after cloud point extraction using nonionic surfactant Triton X-100[J].Analytica Chimica Acta,2007,596(1):62-65.
  • 3CHENG D,LI B X.Simple and sensitive fluorometric sensing of malachite green with native double-stranded calf thymus DNA as sensing material[J].Talanta,2009,78(3):949-953.
  • 4Afkhami A,Moosavi R,Madrakian T.Preconcentration and spectrophotometric determination of low concentrations of malachite green and leuco-malachite green in water samples by high performance solid phase extraction using maghemite nanoparticles[J].Talanta,2010,82(2):785-789.
  • 5Martínez Bueno M J,Herrera S,Uclés A,et al.Determination of malachite green residues in fish using molecularly imprinted solid-phase extraction followed by liquid chromatography-linear ion trap mass spectrometry[J].Analytica Chimica Acta,2010,665(1):47-54.
  • 6TAO Y F,CHEN D M,CHAO X Q,et al.Simultaneous determination of malachite green,gentian violet and their leuco-metabolites in shrimp and salmon by liquid chromatography-tandem mass spectrometry with accelerated solvent extraction and auto solid-phase clean-up[J].Food Control,2011,22(8):1 246-1 252.
  • 7SHEN Y D,DENG X F,XU Z L,et al.Simultaneous determination of malachite green,brilliant green and crystal violet in grass carp tissues by a broad-specificity indirect competitive enzyme-linked immunosorbent assay[J].Analytica Chimica Acta,2011,707(1/2):148-154.
  • 8Lee S,CHOI J,CHEN L,et al.Fast and sensitive trace analysis of malachite green using a surface-enhanced Raman microfluidic sensor[J].Analytica Chimica Acta,2007,590(2):139-144.
  • 9LIANG H,SONG D D,GONG J M,et al.Signal-on electrochemiluminescence of biofunctional Cd Te quantum dots for biosensing of organophosphate pesticides[J].Biosensors and Bioelectronics,2014,53:363-369.
  • 10Beloglazova N V,Speranskaya E S,WU A,et al.Novel multiplex fluorescent immunoassays based on quantum dot nanolabels for mycotoxins determination[J].Biosensors and Bioelectronics,2014,62:59-65.

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化学工程师
2011年 第8期

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