摘要
A novel inorganic-organic compound （C4N2H12）（C2N2H10）2[Mo5P2O23] （1） has been synthesized by the reaction of （NH4）2MoO4, H3PO4, C2N2H8 （ethylenediaminium）, C4N2H10·6H2O （piperazine hexahydrate） and water in aqueous solution under mild hydrothermal conditions. Single-crystal X-ray analysis reveals that the title compound is crystallized in the triclinic system, space group P1 with a = 9.258（19）, b = 9.382（19）, c = 17.681（4）, α = 76.28（3）, β = 84.48（3）, γ = 70.82（3）o, V = 1408.9（6）3, Mr = 1122.04, Z = 2, Dc = 2.645 g/cm3, μ = 2.384 mm-1, F（000） = 1092.0, the final R = 0.0391, wR = 0.1185 and S = 1.006 for 6169 observed reflections with I 2σ（I）. The crystal packing is stabilized by intra- and intermolecular N–H···O hydrogen bonds to form an infinite 3D network.
A novel inorganic-organic compound （C4N2H12）（C2N2H10）2[Mo5P2O23] （1） has been synthesized by the reaction of （NH4）2MoO4, H3PO4, C2N2H8 （ethylenediaminium）, C4N2H10·6H2O （piperazine hexahydrate） and water in aqueous solution under mild hydrothermal conditions. Single-crystal X-ray analysis reveals that the title compound is crystallized in the triclinic system, space group P1 with a = 9.258（19）, b = 9.382（19）, c = 17.681（4）, α = 76.28（3）, β = 84.48（3）, γ = 70.82（3）o, V = 1408.9（6）3, Mr = 1122.04, Z = 2, Dc = 2.645 g/cm3, μ = 2.384 mm-1, F（000） = 1092.0, the final R = 0.0391, wR = 0.1185 and S = 1.006 for 6169 observed reflections with I 2σ（I）. The crystal packing is stabilized by intra- and intermolecular N–H···O hydrogen bonds to form an infinite 3D network.
基金
supported by the Science and Technology Development Foundation of Fujian Province (JA09227)
