摘要
We have reported that phenyliodonium diacetate[PhI(OAc)2] can serve as an eco-friendly mild oxidant for the epoxidation of alkenes in the presence of Mn(III) complex of meso-tetrakis(4-methoxyphenylporphyrin) acetate Mn[(T4-OCH3P)P]OAc and imidazole in CH2Cl2.The amounts of the products(%) and selectivities are very dependent upon the electronic and steric properties of the starting alkenes.To evaluate the validity of this catalytic system for C "H activation,cyclohexane and ethylbenzene were oxidized under the epoxidation conditions.
We have reported that phenyliodonium diacetate[PhI(OAc)2] can serve as an eco-friendly mild oxidant for the epoxidation of alkenes in the presence of Mn(III) complex of meso-tetrakis(4-methoxyphenylporphyrin) acetate Mn[(T4-OCH3P)P]OAc and imidazole in CH2Cl2.The amounts of the products(%) and selectivities are very dependent upon the electronic and steric properties of the starting alkenes.To evaluate the validity of this catalytic system for C "H activation,cyclohexane and ethylbenzene were oxidized under the epoxidation conditions.
基金
Supported by the Yasouj University Research Council and Department of Chemistry of Yasouj University,Iran