期刊文献+

新型胆固醇侧部衍生物的合成研究

Study on synthesis of new type of side cholesteric derivatives
下载PDF
导出
摘要 对胆固醇的双键进行环氧化,然后分别用4-溴丁酸、5-溴戊酸和6-溴己酸进行开环氧化,将柔性链键接到胆固醇的腰上,再分别与甲基丙烯酸钾进行反应,得到了3个新型的含柔性链腰接胆固醇的甲基丙烯酸酯衍生物单体,从而为合成新型的含胆固醇衍生物的聚合物研究奠定了基础。 It was firstly discussed that cholesterol was oxidized into epoxy at C5 and C6, followed by an epoxy-ring-opening reaction with 4-bromobutyric acid, 5-bromovaleric acid, and 6-bromohexanoic acid, and the soft chain was attached to cholesterol lateral, then they were reacted with methacrylate potassium salt ultimately. Three new types of synthesized, which was established monomers of methyl methacrylate derivatives of cholesterol lateral were for the investigation of cholesteric derivatives.
作者 王斌 张军华
出处 《应用化工》 CAS CSCD 2011年第8期1307-1309,共3页 Applied Chemical Industry
基金 国家自然科学基金资助项目(20804026)
关键词 胆固醇 侧部 胆固醇衍生物 cholesterol lateral cholesteric derivatives
  • 相关文献

参考文献13

  • 1Kolk Harm-Anton, Julia J, Hwang, et al. Cholesteryl-( L- lactic acid)n building blocks for self-assembling biomaterials [ J ]. Macromolccules ,2002,35:746-759.
  • 2Zhang baoyan, Meng fanbao, Zang baoling, et al. Liquid- crystalline elastomers containing sulfonic acid groups [ J ]. Macromolec ules, 2003,36 : 3320 -3326.
  • 3Chandrasekar K, Vijay R, C, eetha Baskar. Ionic polymeric amphiphiles with cholesterol mesogen:Adsorption and organization characteristics at the air/water interface from langmuir film balance studies [ J ]. Biomacromolecules, 2005,9 : 1264-1272.
  • 4Xu junting, Xue liang, Fan zhiqiang. Competition of crys- talline and liquid crystalline moieties in self-assembly of poly ( oxyethylene ) cholesterol ethers [ J ]. Macromole- cules,2006,39:2981-2988.
  • 5Kiyonobu Kishihara,Jing Bingwen, Steven L Regen. Ches- terol-modulated lipid-peptide communication in fluid bilayers[ J]. Langmuir,2002,18:9635-9637.
  • 6Praveen Kumar Vemula, V Ajay Mallia, Kujtim Bizati, et al. Cholesterol phenoxy hexanoate mesogens: Effect of me- ta substituents on their liquid crystalline behavior and in situ metal nanoparticle synthesis[ J]. Chem Mater,2007, 19:5203-5206.
  • 7Chandrasekar K, Geetha Baskar. Cholesterol mesogen con- taining water-soluble copolymers : Design and oganization behavior at different interfaces [ J ]. Biomaeromolecules, 2007,8 : 1665-1675.
  • 8Soon Wook Cha, Jin Jung-I, Kim Dae-Cheol, et al. Com- bined type liquid crystalline poly(oxy-1,4-phenyleneoxy- terephthaloyl)s bearing cholesterol pendants attached through polymethylene spacers [ J ]. Macromolecules, 2001,34:5342-5348.
  • 9Zhang baoyan, Mcng fanbao, Li qianyuc, et al. Effect of sulfonic acid containing mesogens on liquid-crystalline behavior of polysiloxane-based polymers [ J ]. Langmuir, 2007,23:6385-6390.
  • 10Tomohiro Seki, Shiki Yagai, Takashi Karatsu, et al. Forma- tion of supramolecular polymers and discrete dimers of perylene bisimide dyes based on melamine-cyanurates hy- drogen-bonding ineraetion [ J ]. J Org Chem, 2008,73 : 3328-3335.

相关作者

内容加载中请稍等...

相关机构

内容加载中请稍等...

相关主题

内容加载中请稍等...

浏览历史

内容加载中请稍等...
;
使用帮助 返回顶部