期刊文献+
任意字段
题名或关键词
题名
关键词
文摘
作者
第一作者
机构
刊名
分类号
参考文献
作者简介
基金资助
栏目信息

BiFeO_3-PbTiO_3系高温压电陶瓷的阻抗谱分析 被引量：4

Impedance Spectroscopy Study of High Temperature BiFeO_3-PbTiO_3 Based Ceramics
下载PDF
导出
摘要 采用交流阻抗谱分析0.63(Bi_(0.94)La_(0.06))(Ca_(0.05)Fe_(0.95))O_3-0.37PbTiO_3(BLGF-PT)高温压电陶瓷的导电机制.阻抗谱和模谱分析表明,BLGF-PT的绝缘性能主要由晶粒贡献,BLGF-PT陶瓷的电学等效电路可以用一个电阻和一个通用电容器并联构成.由阻抗谱计算得出的晶粒电阻率随温度的升高而下降,载流子的激活能为0.88 eV. Impedance spectroscopy has been used to investigate the conduction mechanism in the high I ~ temperature ceramics 0. 63 （ Bio.94 La0.o6 ） （ Ga0.05 Feo.95 ） 03-0. 37PbTiO3 （BLGF-PT）. The anlysls of impedance and modulus spectroscopy has revealed that the region of grains is the most resistive component in the sample. Also, the electrical properties of BLGF-PT ceramics are demonstrated, which can be represented using a parallel combination of a resistor and a universal capacitor. Resistivity of grains extracted from complex impedance plots decrease with the increase of temperature, and the calculated activation energy Ea is 0.88 eV.
作者 程晋荣 石贵阳 祁玉发 陈建国 俞圣雯
机构地区 上海大学材料科学与工程学院
出处 《上海大学学报（自然科学版）》 CAS CSCD 北大核心 2011年第4期535-540,共6页 Journal of Shanghai University:Natural Science Edition
基金 国家自然科学基金资助项目(50472098,50711130241) 上海市教委基金资助项目(08SG41) 上海市纳米专项基金资助项目(1052NM07300)
关键词 阻抗谱 高温压电陶瓷 等效电路 导电机制 impedance spectroscopy high temperature ceramic equivalent circuit conductionmechanism
分类号 TM228 [一般工业技术—材料科学与工程]
  • 相关文献

参考文献22

  • 1EITEL R E, RANDALL C A, SHROUT T R, et al. New high temperature morphotropic phase boundary piezoelectrics based on Bi (Me) O3-PbTiO3 ceramics [J]. Jpn J Appl Phys, 2001, 40:5999-6002.
  • 2EITEL R E, RANDALL C A, SHROUT T R, et al. Preparation and characterization of high temperature perovskite ferroelectrics in the solid-solution (1-x) BiScO3-xPbTiO3 [J]. Jpn J Appl Phys, 2002, 41:2099- 2104.
  • 3CHENG J R, ZHU W Y, LI N, et al. Fabrication and characterization of xBiGaO3-(1 -x) PbTiO3 : a high temperature reduced Pb-content piezoelectric ceramic [J]. Mater Lett, 2003, 57:2090-2094.
  • 4CHENG J R, EITEL R E, LI N, et al. Structure and electrical properties of (1-x) Bi (Ga1/4 Sc3/4 ) O3- xPbTiO3 piezoelectric ceramics [ J]. J Appl Phys, 2003, 94 ( 1 ) : 605-609.
  • 5STERIANOU I, REANEY I M, SINCLAIR D, et al. High- temperature (1-x) Bi ( Sc1/2 Fe1/2 ) O3-xPbTiO3 piezoelectric ceramics [ J ]. Appl Phys Lett, 2005, 87 : 242901.
  • 6CHENG J R, MENG Z, CROSS L. E, et al. High-field and high-Tc piezoelectric ceramics based on Bi (Ga, Fe) Q-PbTiO3 crystalline solutions [ J ]. J Appl Phys, 2005, 98:084102.
  • 7FEDULOV S A, I,ADYZHINSKII P B, PYATIGORSKAYA I L, et al. Complete phase diagram of the PbTiO3-BiFeO3 system [ J ]. Sov Phys Solid State, 1964, 6 (2) : 375- 377.
  • 8SUNDER V V S S S, HALLIYAL A, UMARIJ A M. Investigation of tetragonal distortion in the PbTiO3- BiFeO3 system by high-temperature X-ray diffraction[ J ]. J Mater Res, 1995, 10(5) : 1301-1306.
  • 9COMYN T P, MCBRIDE S P, BELL A J. Processing and electrical properties of BiFeO3-PbTiO3 ceramics [ J].Mater Lett, 2004, 58:3844-3846.
  • 10NJIWA A B K, AULBACH E, RODEL J, et al. Ferroelasticity and R-curve behavior in BiFeO3-PbTiO3 [J]. J Am Ceram Soc, 2006, 89:1761-1763.

同被引文献61

  • 1尧彬,张树人,周晓华,唐斌.CBS掺杂对钛酸钡陶瓷介电性能的影响[J].电子元件与材料,2006,25(4):20-23. 被引量：9
  • 2G.Yao, X.Wang, T.Sun, L.Li, Effects of CaZrO3 on X8R nonreducible BaTiO3-Based dielectric ceramics, J. Am. Ceram. Soc., 94(11), 3856(2011).
  • 3L.A.Dunyushkina, S.V.Plaksin, A.A.Pankratov, L.A.Kuz'mina, V.M.Kuimov, V.P.Gorelov, Synthesis and Properties of CaZrO3 Films on YSZ Electrolyte Surface, Russ. J. Electrochem., 47(11), 1274(2011).
  • 4D.Janke, Oxygen probes based on calcia-doped hafnia or calcium zirconate for use in metallic melts, Metall. Trans., 13B, 227(1982).
  • 5M.Dudek, Usefulness of gel-casting method in the fabri- cation of nonstoichiometric CaZrO3-based electrolytes for high temperature application, Mater. Res. Bull., 44(8), 1879(2009).
  • 6G.Rog, A. Kozlowska-RSg, M.Dudek, The standard Gibbs free energy of formation of calcium chromium (HI) oxide in the temperature range (1073 to 1273 K), J. Chem. Ther- modynamics., 39(2), 275(2007).
  • 7G.Rog, M.Dudek, A.Kozlowska.RSg, M.Budko, Calcium zirconate: preparation, properties and application to the solid oxide galvanic cells, Electrochimica. Acta., 47(28), 4523(2002).
  • 8M.Dudek, Miroslaw M.Budko, Electrical properties of stoi- chiometric and non-stoichiometric calcium zirconate, Solid State Ionics., 157(1-4), 183(2003).
  • 9S.C.Hwang, G.M.Choi, The effect of cation nonstoichiom- etry on the electrical conductivity of CaZrO3, J. Eur. Ce- ram. Soc., 25(12), 2609(2005).
  • 10S.C.Hwang, G.M.Choi, The mixed ionic and electronic conductivity of CaZrO3 with cation nonstoichiometry and oxygen partial pressure, Solid State Ionics., 179(21-26), 1042(2008).

引证文献4

上海大学学报（自然科学版）
2011年 第4期

相关作者

内容加载中请稍等...

相关机构

内容加载中请稍等...

相关主题

内容加载中请稍等...

浏览历史

内容加载中请稍等...
;
使用帮助 返回顶部