摘要
以层状双金属氢氧化物(LDHs)为主体,半胱氨酸(Cys)为修饰剂,制备Cys表面修饰LDHs(Cys-LDHs),之后利用胶体沉积技术在铜表面制备Cys-LDHs薄膜。采用电化学阻抗谱(EIS)、极化曲线的方法研究修饰前后LDHs薄膜在质量分数3.5%NaCl溶液中对铜的缓蚀性能。结果表明,2种LDHs薄膜对铜均具有良好的缓蚀效果,且Cys-LDHs薄膜的缓蚀效果更佳,缓蚀效率可达91.4%。
In this paper,LDHs were modified with cysteine(Cys) to prepare Cys-LDHs.The Cys-LDHs film was prepared on copper surfaces by a colloid deposition technique.The corrosion inhibition of the formed film was studied by electrochemical impedance spectroscopy(EIS) and polarization curves.All results demonstrate that both LDHs and Cys-LDHs films could inhibit the corrosion of copper,and the Cys-LDHs films showed significantly higher inhibition efficiency,reaching 91.4%.
出处
《青岛科技大学学报(自然科学版)》
CAS
2011年第4期356-360,共5页
Journal of Qingdao University of Science and Technology:Natural Science Edition
关键词
表面修饰
LDHs薄膜
缓蚀
铜
surface modified
LDHs film
anti-corrosion
copper