期刊文献+

乙腈市场需求情况与技术分析 被引量:1

Analysis on market demand and production technologies of acetonitrile
下载PDF
导出
摘要 介绍了乙腈的用途及市场需求情况,综述了国内外合成乙腈的主要工艺方法,在与乙酸氨化路线、乙醇氨氧化路线对比分析的基础上,着重分析了乙醇脱氢氨化法合成乙腈技术,结果表明,用乙醇作为原料直接合成乙腈,原料相对易得、价格低廉,设备腐蚀性小,并且可以副产氢气。从长远来看,只要开发出高效的催化剂,乙醇脱氢氨化合成乙腈技术更有工业应用前景。 The application and market demand of acetonitrile are presented, and the domestic and overseas advances in production technonlgies of acetonitrile are reviewed. Based on comparing with ammonolysis of acetic acid and ammoxidation of eth anol, the synthesis of acetonitrile by ethanol dehydrogenation ammoniation is analyzed emphatically, owing to easily available and cheap raw materials, slight corrosion to equipment and by-produced hydrogen gas. In the long term, as long as the high efficient catalyst is developed, the industrial prospects of synthesis of acetonitrile by ethanol dehydrogenation amination wilt be more promising.
出处 《化学工业与工程技术》 CAS 2011年第4期48-51,共4页 Journal of Chemical Industry & Engineering
基金 黑龙江省自然科学基金(73969524-2-10001)
关键词 乙醇 乙腈 催化剂 Ethanol Acetonitrile Catalyst
  • 相关文献

参考文献13

  • 1吴伟龙,陈水林.乙腈生产及其在工业上的主要利用[J].山东化工,2004,33(6):26-27. 被引量:10
  • 2匡洞庭,黄付玲,盖延军.乙腈合成新工艺简述[J].油气田地面工程,2004,23(5):54-54. 被引量:8
  • 3汪多仁.乙腈生产新工艺[J].四川化工,1995(1):60-61. 被引量:4
  • 4潘伟雄.用于由乙醇与氨合成乙腈的催化剂[P]中国专利:CN1062303.
  • 5吴粮华,赵乐,汪国军.氨氧化生产乙腈的流化床催化剂[P]中国专利:CN1765879.
  • 6GALANOV S I,SIDOROVA O I,KURINA L N,etal.Catalytic synthesis of acetonitrile. Kataliz v Pro-myshlennosti . 2004
  • 7GALANOV S I,SIDOROVA O I,KURINA L N,etal.Catalytic synthesis of acetonitrile by ammonolysisof acetic acid. Neftekhimiya . 2003
  • 8CARD R J,SCHMITT J L.Gas-phase synthesis ofnitriles. Journal of Organic Chemistry . 1981
  • 9Yining Zhang,Yucheng Zhang,Feng Chenget al.Amination of ethanol to acetonitrile over Ni-Co/γ-Al2O3catalyst. Catalysis Communications . 2009
  • 10Roger J C,Schmitt J L.Catalysts for selective preparation of amines or nitriles from alkanols. US,4654440 . 1987

二级参考文献4

共引文献11

同被引文献19

引证文献1

二级引证文献2

相关作者

内容加载中请稍等...

相关机构

内容加载中请稍等...

相关主题

内容加载中请稍等...

浏览历史

内容加载中请稍等...
;
使用帮助 返回顶部