摘要
探讨了抗氧剂、阻燃剂、增韧剂对增强阻燃PBT抗黄变性的影响.结果表明,含硫抗氧剂对改善增强阻燃PBT抗黄变的效果比亚磷酸脂抗氧剂显著;阻燃剂容易吸附抗氧剂,从而削弱了抗氧剂的作用,添加多官能团助剂可有效缓解该问题.引入0.5%多官能团助剂后,增强阻燃PBT热老化后的色差比未加多官能团助剂时降低了39.6%,而且其热老化后的拉伸强度、弯曲强度、缺口冲击强度保持率分别提高了10.0%、10.7%、6.8%.加入处理的增韧剂可有效地降低玻纤增强阻燃PBT的端羧基浓度,并可提高其抗黄变性.
The effect of antioxidant, flame retardant and plasticizer on the yellowing resistance of reinforced flame retardant PBT composites was studied. Compared with a phosphite antioxidant, the sulfur-containing antioxidant had better improvement on the yellowing resis- tance of reinforced flame retardant PBT composites. Flame retardants would adsorb the antioxidant easily and weaken the oxidation efficiency, which could be eased by the poly-functional group additive. The color difference of reinforced flame retardant PBT after the heat aging declined 39.6 % by introducing the poly-functional group additive, and the tensile strength, flexural strength and impact fracture after the heat aging enhanced 10%, 10. 7%, 6.8% respectively. The carboxylic end group concentration of glass fiber reinforced flame retardant PBT would be declined effectively by introducing the treated plasticizer, which could improve its yellowing resistance.
出处
《南开大学学报(自然科学版)》
CAS
CSCD
北大核心
2011年第4期72-76,共5页
Acta Scientiarum Naturalium Universitatis Nankaiensis
基金
福建省教育厅(A)类项目(JA09246)
关键词
增强阻燃PBT
抗黄变性
多官能团
端羧基浓度
reinforced flame retardant PBT
yellowing resistance
poly-functional group
carboxylic end group concentration