三种快速测定石油污水中COD方法的比较

Comparison of three methods for determination of chemical oxygen demand of petroleum polluted water

以新疆乌鲁木齐石化总厂石油污水研究对象,采用标准法从消解时间、取样量、催化剂用量三方面考察测定了COD的最佳实验条件,并在两实验室间验证其可靠性。分别利用重铬酸钾快速法、密封消解法、HACH法测定石油污水的COD值,并与标准法进行比对。结果表明:(1)取样量相同时,重铬酸钾快速法比标准法耗酸量还要多,仅仅只是缩短了回流时间;(2)密封消解法具有省时、省试制、工作效率高的特点,可以作为标准法的替代方法;(3)HACH方法在实际操作中不经济。

The national standard method was used to detect chemical oxygen demand of petroleum -polluted water from Urumchi petrochemistry company.The elimination time, sample Volume and catalyst consumption of the chemical oxygen demand was determined. The optimal experimental condition of the were determined and verified by practical water sample between two Laboratories.Three kinds of methods were Compared with the standard method.It was shown that.（1）In the same condition,The catalyst amount of K_2Cr_2O_7 rapid detecting were more than national standard.（2）the standard method was replaced of the sealed elimination by saving time,saving drugs and high efficiency.（3）In practice,HACH was uneconomic.