摘要
The two independent cations of the salt, [HO-C6H4-CH=NH-C6H4-OH]·1/2OH·1/2Cl, are both disordered about an axis connecting the two oxygen atoms at the para-positions of the aromatic rings, the disorder being in a 83：17 ratio in one cation and 91：9 in the other. The hydroxide and chloride anions are ordered. The treatment of the nearly ‘whole-molecule disorder’ by employing a small number of restraints is described. Crystal data： C13H12.5Cl0.5NO2.5, triclinic, P , a = 9.1731（4）, b = 9.2048（4）, c = 15.9144（7） , α = 104.822（1）, β = 90.077（1）, γ = 118.641（1）o and V = 1127.86（9） 3 at –173 K.
The two independent cations of the salt, [HO-C6H4-CH=NH-C6H4-OH]·1/2OH·1/2Cl, are both disordered about an axis connecting the two oxygen atoms at the para-positions of the aromatic rings, the disorder being in a 83：17 ratio in one cation and 91：9 in the other. The hydroxide and chloride anions are ordered. The treatment of the nearly ‘whole-molecule disorder’ by employing a small number of restraints is described. Crystal data： C13H12.5Cl0.5NO2.5, triclinic, P , a = 9.1731（4）, b = 9.2048（4）, c = 15.9144（7） , α = 104.822（1）, β = 90.077（1）, γ = 118.641（1）o and V = 1127.86（9） 3 at –173 K.
