摘要
The new complex, [Co2（adc）2（py）4（H2O）}n 1 （adc = 1,3-adamantanedicarboxylate, py = pyridine）, has been hydrothermally synthesized as polymeric solid, and characterized by X-ray diffraction, elemental analysis, IR spectra and thermogravimetric analysis. Complex 1 crystallizes in monoclinic, space group C2/c with a = 18.932（4）, b = 19.779（4）, c = 12.352（3） , β = 112.03（3）o, V = 4288（2） 3, Z = 4, GOF = 0.998, R = 0.0518 and wR = 0.1074. X-ray single-crystal analysis reveals that 1 presents a 3D simple parallel rod-like supramolecular array constructed by 1D tape-like polymeric motif through aromatic π-π stacking interaction. Electrochemical investigation shows that 1 exhibits appreciable electrocatalytic activity for the reduction reaction of nitrite.
The new complex, [Co2（adc）2（py）4（H2O）}n 1 （adc = 1,3-adamantanedicarboxylate, py = pyridine）, has been hydrothermally synthesized as polymeric solid, and characterized by X-ray diffraction, elemental analysis, IR spectra and thermogravimetric analysis. Complex 1 crystallizes in monoclinic, space group C2/c with a = 18.932（4）, b = 19.779（4）, c = 12.352（3） , β = 112.03（3）o, V = 4288（2） 3, Z = 4, GOF = 0.998, R = 0.0518 and wR = 0.1074. X-ray single-crystal analysis reveals that 1 presents a 3D simple parallel rod-like supramolecular array constructed by 1D tape-like polymeric motif through aromatic π-π stacking interaction. Electrochemical investigation shows that 1 exhibits appreciable electrocatalytic activity for the reduction reaction of nitrite.
基金
supported by the National Natural Science Foundation of China (No. 50971063)
the Natural Science Foundation of Fujian Province (2003F006, 2010J01042)
the Scientific Research Foundation for the Returned Overseas Chinese Scholars, State Education Ministry of China
