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侧基官能性乙烯基醚阳离子活性聚合与乙烯基醚阳离子光固化体系 被引量:1

Advances in Cationic Polymerization of Vinyl Ether with Functional Pendant Group Research
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摘要 本文着重介绍阳离子聚合单体的结构、溶剂及引发体系对活性阳离子聚合技术的影响以及近几年来采用活性阳离子聚合技术制备侧基官能性乙烯基醚聚合物的方法,尤其是应用较广泛的羟基、羧基、氨基等侧基官能化聚合物的合成。研究乙烯基醚阳离子活性聚合,将对乙烯基醚阳离子光固化体系的应用研究具有重要的指导意义。 The influence factors such as the structure of cationic monomer, solvent used in reaction and initiating system on the active cationic polymerization were introduced. The mothods in preparation of vinyl ether polymer with functional side groups by cationic polymerization, especially the vinyl ether with a hydroxyl, a carhoxyl or an amino group were sumarrized. Studying the acitve cationic polymerization of vinyl ethers has important guiding significance for the application of cationic light curing system of vinyl ether.
出处 《信息记录材料》 2011年第5期52-55,共4页 Information Recording Materials
基金 北京市自然科学基金 编号2112020
关键词 活性阳离子聚合 电子效应 位阻效应 引发体系 侧基官能性乙烯基醚 active cationic polymerization electronic effect steric effect vinyl ether functional pendant group
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  • 1Wu Guanying,Man Xinghua,Cheng Bin.The role of complexation in living cationic polymerization with Lewis acid/ester systems[J]. Polymer Bulletin . 1989 (4)
  • 2Mitsuo Sawamoto,Masami Kamigaito,Kazushige Kojima,Toshinobu Higashimura.Living cationic polymerization of isobutyl vinyl ether initiated by the trimethylsilyl iodide/zinc iodide system[J]. Polymer Bulletin . 1988 (4)
  • 3Toshinobu Higashimura,Yasuhisa Kishimoto,Sadahito Aoshima.Living cationic polymerization of vinyl monomers by organoaluminum halides[J]. Polymer Bulletin . 1987 (2)
  • 4Sadahito Aoshima,Toshinobu Higashimura.Living cationic polymerization of vinyl monomers by organoaluminium halides[J]. Polymer Bulletin . 1986 (5)
  • 5Szwarc M. Nature . 1956
  • 6Szwarc M,Levy M,Mikovich R. Journal of the American Ceramic Society . 1956
  • 7Kennedy J P. Science in China Series B Chemistry . 1982
  • 8Higashimura T,Kishiro O,Takeda T. Journal of Polymer Science Part A Polymer Chemistry . 1976
  • 9Masuda T,Sawamoto M,Higashimura T. Macromolecular Chemistry and Physics . 1976
  • 10Othtori T,Hirokawa Y,Higashimura T. Polymer Journal . 1979

同被引文献18

  • 1Verebelyi K,Ivdn B. Cationic polymerization of styrene by the TiCl4/N,N, N、N'-tetramethylethylenediamine(TMEDA)catalyst system in benzotrifluoride an environmentally benign solvent at room temperature[J]. Polymer, 2012,53(16) j3426-3431.
  • 2Holbrey J D, Seddon K R. Ionic liquids[J]. Clean Products and Processes 1,1999 (1) ? 223-236.
  • 3Ambler P W,Hodogson P K G, Stewart N J,et al. Butene polymers:EP,0558187[P], 1993-01-29.
  • 4Perrier S,Davis T,Carmiehacl A,et al. Reversible additio*fragmentation chain transfer polymerization of methacrylate,acrylate and styrene monomers in l-alkyl-3-methylimidazolium hexfluorophosphate[J]. European Polymer Journal, 2003,39(3) : 417-422.
  • 5Kokubo H,Watanabe M. Anionic polymerization of methyl methacrylate in an ionic liquid [ J]. Polymers advancedtechnologies, 2008,19(10) : 1441-1444.
  • 6Vijayaraghavan R, Pringle J M,MacFarlane D R. Anionic polymerization of styrene in ionic liquids [J]. EuropeanPolymer Journal,2008, 44(6) : 1758-1762.
  • 7Biedron T,Kubisa P. Cationic polymerization of styrene in a neutral ionic liquid[J]. Journal of Polymer Science Part A:Polymer Chemistry, 2004,42(32):30-35.
  • 8Basko M,Tadeusz,Kubisa Przemyslaw. Cationic polymerization of styrene involving ionization of the CC1 bond in ionicliquid/S02 mixture[J], Journal of Polymer Science: Part A: Polymer Chemistry, 2009,47(20) :5251-5257.
  • 9Ranganathan Vijayaraghavan? Douglas MacFarlane. Living cationic polymerisation of styrene in an ionic liquid[J].Chemical Communications, 2004(6) ; 700-701.
  • 10Priyadarsi De, Rudolf Faust. Living carbocationic polymerization of 多-methoxystyrene using /)-methoxystyrenehydrochloride/SnBr4 initiating system: determination of the absolute rate constant of propagation for ion pairs [J].Macromolecules,2004, 37(21):7930-7937.

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