甲烷氧等离子体直接合成过氧化氢

Direct Synthesis of H_2O_2 Using Methane-oxygen Plasma

过氧化氢（H2O2）是一种重要的绿色氧化剂.传统的H2O2合成工艺（蒽醌法）需多步操作,产生大量废水并且消耗较高的能量.近年来,多采用H2和O2为原料一步法直接合成H2O2,其中基于负载型贵金属催化剂的合成路线已取得较好的结果.

A non-thermal atmospheric pressure plasma by dielectric barrier discharge was used to study the direct oxidation of methane to hydrogen peroxide.The effects of the structure of plasma reactors,as well as the ratio of CH4 to O2,were investigated.It is observed that at room temperature and atmospheric pressure,methane and oxygen can be directly converted into hydrogen peroxide with high yield.When a double dielectric barrier discharge（DDBD） plasma reactor is fed with a CH4/O2 mixture containing 50%（volume fraction） at a total flow rate of 50 mL/min（CH4＋O2）,it generates H2O2 with 29.2% yield and the H2O2 formation efficiency is estimated to be 221.6 g/m3（CH4/O2）.The high H2O2 yield obtained by CH4/O2 plasma method may be attributed to the nonequilibrium property of non-thermal plasma that the electron energy inside the conductive filament corresponds to a few electron volt,while the gas temperature stays close the temperature of the background gas.As a result,the energetic electrons in the plasma region collide with molecules and atoms of the CH4/O2 mixture and generate excited species,atoms,as well as other molecular fragments that initiate the ensuing chemical reactions and produce H2O2,while the thermal decomposition of H2O2 is neglectable because of low gas temperature.