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微波辐射合成5,12-二氢-5,7,12,14-四氮杂并五苯 被引量：1

Microwave-assisted synthesis of 5,12-dihydro-5,7,12,14-azapentacene
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摘要 以微波辐射辅助的方法合成5,12-二氢-5,7,12,14-四氮杂并五苯,实验证明微波辐射能促进2,3-二羟基吩嗪和邻苯二胺反应。经正交试验分析,确定微波辐射反应最佳条件如下:2,3-二羟基吩嗪和邻苯二胺摩尔比为1∶6;反应时间为150s;2,3-二羟基吩嗪与乙酸量之比为1∶1(mol/mL)。经1H NMR、MS、熔点测定,确定目标产物。 5,12-dihydro-5,7,12,14-azapentacene was synthesized by the microwave radiation method,it was found that microwave radiation can facilitate the reaction of 2,3-dihydroxyphenazine and o-phenylenediamine.According to the orthogonal experiment,the optimum conditions of reaction with microwave radiation were as follows：the mole ratio of 2,3-dihydroxyphenazine and o-phenylenediamine was 1∶6,the reaction time is 150s,the ratio of 2,3-dihydroxyphenazine and acetic acid was 1∶1（mol/mL）.The target compound was characterized by 1H NMR、MS and melting point.
作者 玄光善 张庆珍 姜皓然 刘杰
机构地区 青岛科技大学药学系 山东省眼科研究所
出处 《化学研究与应用》 CAS CSCD 北大核心 2011年第10期1337-1340,共4页 Chemical Research and Application
关键词 微波 合成 5 12-二氢-5 7 12 14-四氮杂并五苯 正交试验 microwave synthesis 5 12-dihydro-5 7 12 14-azapentacene orthogonal experiment
分类号 O626.44 [理学—有机化学]
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参考文献11

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化学研究与应用
2011年 第10期

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