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对甲苯磺酰氯催化的meso-四芳基卟啉的合成 被引量：2

Synthesis of meso-tetraarylporphyrins catalyzed byp-CH_3C_6H_4SO_2Cl
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摘要 报道了一种改进了的meso-四芳基卟啉合成方法。利用对甲苯磺酰氯催化吡咯和芳香醛缩合生成中间物卟啉原,卟啉原中间物在紫外光照射下被空气氧化生成四芳基卟啉。该方法所用催化剂价廉易得,氧化过程绿色。整体反应条件简单,易于操作,产率高。 An efficient and economical synthesis of meso-tetraarylporphyrins was accomplished through p-CH3C6H4SO2Cl（TsCl）catalyzed condensation of pyrrole and aryl aldehydes,and subsequent oxidation by air under ultraviolet（UV）irradiation.The advantages of this method included the use of inexpensive and easily available catalyst,avoidance of heavy consumption of dichloromethane,innocuous oxidant,and good yield.
作者 张倩 王玉炉 段乐 刘凤华 王瑾晔
机构地区 河南师范大学化学与环境科学学院 上海交通大学生物医学工程系
出处 《化学研究与应用》 CAS CSCD 北大核心 2011年第10期1388-1391,共4页 Chemical Research and Application
基金 973国家重点基础研究发展计划项目资助(2005CB724306)
关键词 四芳基卟啉 对甲苯磺酰氯 合成 吡咯 芳香醛 tetraarylporphyrins p-CH3C6H4SO2Cl synthesis pyrrole aromatic aldehydes
分类号 O626.13 [理学—有机化学]
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  • 1Bartoli J F, Brigaud O, Battioni P, et al. Hydroxylation of linear alkanes catalysed by iron porphyfins:particular efficacy and regioselectivity of perhalogenated porphyrins[ J ]. J. Chem. Soc. Chem. Commun. ,1991,440-441.
  • 2Hashem S, Mohammad A N,Alireza H N. Efficient synthesis of β-hydroxy thiocyanates from epoxides and ammonium thiocyanates using tetraarylporphyrins as new catalysts [ J ]. J. Mol. Catal. A : Chem. ,2003,206:53-57.
  • 3Wasielewski M R. Photoinduced electron transfer in supramolecular systems for artificial photosynthesis[J].Chem. Rev. ,1992,92(3) :435-461.
  • 4Seixas de Melo J, Sobral Abllio J F N, Rocha Gonsalves A M d' A, et al. Singlet and triplet energy transfer in a bichromophoric system with anthracene covalently linked through sulfonamide to a meso-tetraphenylporphyrin [ J ]. J. Photoch Photobio A Chem. , 2005,172 : 151-160.
  • 5Drain C M, Russell K C, Lehn J M. Synthesis, structure and reactivity of ionogenic Sn ( -CpR ) Cl derivatives [ J ] . J. Chem. Soc. Chem. Cornmun. ,1996,2337-2338.
  • 6Guo L Q, Zhang W, Xie Z H. et al. An organically modified sol - gel membrane for detection of mercury ions by using 5,10,15,20-tetraphenylporphyrin as a fluorescence indicator[ J ]. Sensor Actuat. B Chem. ,2006,119:209-214.
  • 7Wiene A, Shaker Y M, Brandt J C, et al. Lead stnJctures for applications in photodynamic therapy. Part 1 :Synthesis and variation of m-THPC(Temoporfin) related amphiphilic A2BC-type porphyrins [ J ] . Tetrahedron, 2005,61 : 5535- 5564.
  • 8dler A D,Longo F R,Finarelli J D,et al. A simplified synthesis for meso-tetraphenylporphine[ J].J. Org. Chem. , 1976, 32(2) :476.
  • 9Li F,Yang K,Tyhonas J S,et al. Beneficial effects of salts on an acid-catalyzed condensation leading to porphyrin formarion [ J ]. Tetrahedron, 1997,53 : 12339-12360.
  • 10Wagner R W, Johnson T E, Lindsey J S. Investigation of the one-flask synthesis of porphyrins bearing meso-linked straps of variable length ,rigidity,and redox activity[ J ]. Tetrahedron, 1997,53:6755-6790.

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化学研究与应用
2011年 第10期

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