摘要
从人工发酵培养的蜜环菌[Armillaria mellea(Vahl.ex Fr.)Quel.属白蘑科(Tricholometaceae)真菌]菌丝体的石油醚提取物中,经硅胶层析分离得到一新的倍半萜醇芳香酸酯类化合物,命名为蜜环菌癸素(armillaripin)。根据光谱(UV,IR,~1HNMR,^(13)CNMR和MS)分析推测其化学结构,并进一步用X-线衍射晶体解析法确证其结构和其相对构型。
A new protoilludane sesquiterpenoid aromatic ester, named armillaripin, C_(24)H_(30)O_6, mp 202～204℃, [α]_D^(15)+l30°(c 0.055, CHCl_3), was isolated from the petroleum ether extract of the artificially cultured mycelium of Armillaria mellea (Vahl. ex Fr.) Quel. (Tricolometaceae) by silica gel chromatography. On the basis of spectral (UV, IR, ~1HNMR ^(13)CNMR and MS) analysis its structure was deduced as Ⅰ and confirmed by single-crystal X-ray analysis.
出处
《药学学报》
CAS
CSCD
北大核心
1990年第5期353-355,共3页
Acta Pharmaceutica Sinica
关键词
蜜环菌
蜜环菌癸素
倍半萜
Armillaria mellea (Vahl. ex Fr.) Quel
Tricholometaceae
Sesquiterpenoid
Armillaripin
