摘要
从催化剂的应用角度,总结了酸、路易斯酸、固体酸性氧化物、强酸性阳离子交换树脂、无机碱、有机碱以及由酸/路易斯酸、路易斯酸/路易斯酸、路易斯酸/路易斯碱等催化体系在催化芳香胺的氰乙基化反应中的应用进展,阐述了芳香胺的氰乙基化反应的酸催化和碱催化机理,并对芳香胺的氰乙基化反应的今后发展方向进行了展望。
Progress on the cyanoethylation of aromatic amines in different catalytic systems,such as the acid,Lewis acid,solid acid oxide,strong acid cation exchange resin,inorganic base,organic base as well as acid/Lewis acid,Lewis acid/Lewis acid,Lewis acid/Lewis base and so on were summarized from the view of application of catalysts,and the catalytic mechanism of the cyanoethylation by acid and base were also discussed.The future development trends of the cyanoethylation of aromatic amines were prospected,too.
出处
《化学通报》
CAS
CSCD
北大核心
2011年第10期909-916,共8页
Chemistry
基金
湖南省科技厅科研基金项目(2007FJ4156)资助
关键词
芳香胺
氰乙基化反应
催化机理
Aromatic amines
Cyanoethylation
Catalytic mechanism