金属苯的亲核加成和芳香亲核取代反应

The Electrophilic Aromatic Addition and Substitution Reactions of Metallabenzenes

近年来有关金属苯亲核反应的研究工作为证实金属苯的芳香性提供了有力的实验证据,发展了经典有机化学的芳香亲核取代反应理论.同时,借助金属苯亲核反应的研究还可获得一系列结构新颖的金属有机化合物.本文就迄今为止已报道的金属苯的亲核加成和芳香亲核取代反应进行了全面的总结.

Significant progress of the nucleophilic aromatic substitution （SNAr） reaction of metallabenzenes has been made in recent years. SN Ar reaction not only can provide strong chemical support for the aromaticity of the metallabenzene rings but also obtain new interesting organometallic complexes. All the SN Ar reactions of metallabenzenes, whieh have been reported, are reviewed in this article.