摘要
The contents and distribution characteristics of ions, n-alkanes, and polycyclic aromatic hydrocarbons in snow pits on the Yuzhufcng (YZF) Glacier and the Xiao Dongkernadi (XDKMD) Glacier are studied. Parameter characteristics and correlation coefficients between ions and two organic compounds are used to explore the possible sources of these chemical compositions. The results indicated that both glaciers are influenced by west wind circulation, but the contents of ions, n-alkanes, and polycyclic aromatic hydrocarbons in the YZF Glacier are higher than in the XDKMD Glacier because of differences in geographical position. The ratios of ∑nC21^-/∑nC22^+ and CPI values (CPI: carbon preference index) indicate that the n-alkanes from natural sources in these two glaciers are mainly derived from higher plants, whereas the contribution from lower organisms was small, also, n-alkanes from anthropogenic sources in the YZF Glacier are higher than in the XDKMD Glacier. The ratios of LPAHs/HPAHs and (Fly+Pyr)/(BghiP+INP) indicate that the polycyclic aromatic hydrocarbons in these two glaciers are mainly derived from low temperature combustion of coal and biomass, and, in the XDKMD Glacier, partially from the vehicle exhaust.
The contents and distribution characteristics of ions, n-alkanes, and polycyclic aromatic hydrocarbons in snow pits on the Yuzhufcng (YZF) Glacier and the Xiao Dongkernadi (XDKMD) Glacier are studied. Parameter characteristics and correlation coefficients between ions and two organic compounds are used to explore the possible sources of these chemical compositions. The results indicated that both glaciers are influenced by west wind circulation, but the contents of ions, n-alkanes, and polycyclic aromatic hydrocarbons in the YZF Glacier are higher than in the XDKMD Glacier because of differences in geographical position. The ratios of ∑nC21^-/∑nC22^+ and CPI values (CPI: carbon preference index) indicate that the n-alkanes from natural sources in these two glaciers are mainly derived from higher plants, whereas the contribution from lower organisms was small, also, n-alkanes from anthropogenic sources in the YZF Glacier are higher than in the XDKMD Glacier. The ratios of LPAHs/HPAHs and (Fly+Pyr)/(BghiP+INP) indicate that the polycyclic aromatic hydrocarbons in these two glaciers are mainly derived from low temperature combustion of coal and biomass, and, in the XDKMD Glacier, partially from the vehicle exhaust.
基金
supported by the Global Change Research Program of China (No.2010CB951404)
the National Natural Science Foundation of China (Grant No.40930526,40801023,40871038)
the West Light Foundation of the Chinese Academy of Sciences (Grant No.290928601)