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Synthesis of(Sr,Eu)CO_3@SiO_2 core-shell-like precursor for alkali earth silicate phosphors 被引量:1

Synthesis of(Sr,Eu)CO_3@SiO_2 core-shell-like precursor for alkali earth silicate phosphors
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摘要 Monodisperse (Sr, Eu)CO3 sphere (the homogenous mixture of Sr2+ and Eu3+ carbonates) was firstly prepared, and then its surface was coated by amorphous SiO2 in the presence of cationic surfactant cetyltrimethylammonium bromide (CTAB) to form (Sr, Eu)CO3@SiO2 core-shell-like precursor. The overall synthesized mechanism was investigated and proposed based on the Fourier transform infrared spec- troscopy (FTIR), X-ray diffraction (XRD) and scanning electron microscopy (SEM). This strategy could be applied to construct core-shell structured precursors for the preparation of alkali earth silicate phosphors. Monodisperse (Sr, Eu)CO3 sphere (the homogenous mixture of Sr2+ and Eu3+ carbonates) was firstly prepared, and then its surface was coated by amorphous SiO2 in the presence of cationic surfactant cetyltrimethylammonium bromide (CTAB) to form (Sr, Eu)CO3@SiO2 core-shell-like precursor. The overall synthesized mechanism was investigated and proposed based on the Fourier transform infrared spec- troscopy (FTIR), X-ray diffraction (XRD) and scanning electron microscopy (SEM). This strategy could be applied to construct core-shell structured precursors for the preparation of alkali earth silicate phosphors.
出处 《Journal of Rare Earths》 SCIE EI CAS CSCD 2011年第10期911-914,共4页 稀土学报(英文版)
基金 supported by the National Hi-Tech R&D Program of China (863 Program, 2010AA03A404, 2011AA03A101) Beijing Natural Science Foundation (2102022) the Hong Kong Polytechnic University Grant (J-BB9R)
关键词 core-shell structure PRECURSOR formation mechanism PHOSPHOR rare earths ] core-shell structure precursor formation mechanism phosphor rare earths ]
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