摘要
A new complex [Zn1.5（dpa）1.5（bim）]2n（dpa = 2,2-diphenic acid,bim = benzimida-zole）1 has been hydrothermally synthesized and structurally characterized by elemental analysis,IR,fluorescence spectrum and single-crystal X-ray diffraction.The complex crystallizes in monoclinic,space group C2/c with a = 18.773（8）,b = 16.560（7）,c = 16.417（9）,β = 94.737（9）o,V = 5086（4）3,C56H36N4O12Zn3,Mr = 1153.00,Dc = 1.506 g/cm3,μ（MoKα）= 1.472 mm1,F（000）= 2344,Z = 4,the final R = 0.0573 and wR = 0.1164 for 2968 observed reflections（I 2σ（I））.It exhibits a one-dimensional chain-like structure and shows luminescent property in the blue region.
A new complex [Zn1.5（dpa）1.5（bim）]2n（dpa = 2,2-diphenic acid,bim = benzimida-zole）1 has been hydrothermally synthesized and structurally characterized by elemental analysis,IR,fluorescence spectrum and single-crystal X-ray diffraction.The complex crystallizes in monoclinic,space group C2/c with a = 18.773（8）,b = 16.560（7）,c = 16.417（9）,β = 94.737（9）o,V = 5086（4）3,C56H36N4O12Zn3,Mr = 1153.00,Dc = 1.506 g/cm3,μ（MoKα）= 1.472 mm1,F（000）= 2344,Z = 4,the final R = 0.0573 and wR = 0.1164 for 2968 observed reflections（I 2σ（I））.It exhibits a one-dimensional chain-like structure and shows luminescent property in the blue region.
基金
Supported by the Science and Technology Research Projects of the Education Office of Jilin Province (No.2011.459)
