摘要
One dinuclear manganese（II）complex [Mn2（C12H8N2）4（C8H5O4）2]（C8H4O4）·H2O has been synthesized with o-phthalic acid and 1,10-phenanthroline.The crystal structure was determined by X-ray diffraction.The crystal belongs to the triclinic system,space group P1 with a = 1.17767（3）,b = 1.22292（2）,c = 1.35860（3）nm,α = 110.5300（10）,β = 97.6140（10）,γ = 93.7300（10）o,V = 1.80307（7）nm3,Dc = 1.404 g/cm3,Z = 2,F（000）= 784,the final GOOF = 1.047,R = 0.0398 and wR = 0.1038.The crystal structure of the title complex consists of one [Mn2（C12H8N2）4（C8H5O4）2]2＋ cation,one uncoordinate o-phthalate anion（C8H4O4）2-and one uncoordinate water molecule.In [Mn2（C12H8N2）4（C8H5O4）2]2＋,the central Mn（II）ion is coordinated by four nitrogen atoms and two oxygen atoms to give a distorted octahedral coordination geometry.The electrochemical property of the title complex was also studied.
One dinuclear manganese（II）complex [Mn2（C12H8N2）4（C8H5O4）2]（C8H4O4）·H2O has been synthesized with o-phthalic acid and 1,10-phenanthroline.The crystal structure was determined by X-ray diffraction.The crystal belongs to the triclinic system,space group P1 with a = 1.17767（3）,b = 1.22292（2）,c = 1.35860（3）nm,α = 110.5300（10）,β = 97.6140（10）,γ = 93.7300（10）o,V = 1.80307（7）nm3,Dc = 1.404 g/cm3,Z = 2,F（000）= 784,the final GOOF = 1.047,R = 0.0398 and wR = 0.1038.The crystal structure of the title complex consists of one [Mn2（C12H8N2）4（C8H5O4）2]2＋ cation,one uncoordinate o-phthalate anion（C8H4O4）2-and one uncoordinate water molecule.In [Mn2（C12H8N2）4（C8H5O4）2]2＋,the central Mn（II）ion is coordinated by four nitrogen atoms and two oxygen atoms to give a distorted octahedral coordination geometry.The electrochemical property of the title complex was also studied.
基金
Sponsored by the Scientific Research Fund of Hunan Provincial Education Department (B21018)
the Construct Program of the Key Disciplines in Hunan Province
