期刊文献+

MgO催化丙酮气相缩合制3,5-二甲基苯酚的研究 被引量:2

Investigation on Vapor Phase Condensation of Acetone to 3,5-Xylenol by MgO as Catalyst
下载PDF
导出
摘要 以MgO固体碱为催化剂,采用加压气固相催化反应装置,对连续流管式反应炉中丙酮气相一步缩合制3,5-二甲基苯酚的反应进行了研究.考察了温度、时间、压力和溶剂等因素对丙酮转化率和产物选择性的影响.实验得出反应适宜的温度为500℃,压力为0.5 MPa;在氢气氛围、空速为2.4 h-1条件下,使用环己烷和水的混合液为反应溶剂时,丙酮单程转化率为42.4%,目标产物3,5-二甲基苯酚的选择性达33.8%. To obtain 3,5-xylenol by one-step vapor phase condensation of acetone in continuous flow pipe was studied in this paper,which adopts MgO solid base as catalyst with a fixed-bed reactor.The impact of various reaction parameters such as temperature,pressure,time,and solvent were considered.The test results show that MgO catalyst was found to be preferred in condensation of acetone under the optimum conditions of 500 ℃ reaction temperature,and 0.5 MPa reaction pressure.When a mixture of cyclohexane and water used as solvent,the conversion of acetone reached to 42.4% and the selectivity of 3,5-xylenol reached to 33.8% under the conditions of H2 protection and space velocity of 2.4 h-1.
出处 《湖南师范大学自然科学学报》 CAS 北大核心 2011年第5期66-69,共4页 Journal of Natural Science of Hunan Normal University
基金 国家自然科学基金资助项目(20976043,21003043) 湖南省自然科学基金资助项目(09JJ5006) 湖南省高校创新平台开放基金资助项目(09K027) 湖南师范大学青年基金资助项目(21101)
关键词 3 5-二甲基苯酚 丙酮 缩合 固体碱 一步法 3 5-xylenol acetone condensation solid base one-step method
  • 相关文献

参考文献16

  • 1RIEVE R W. Vapor phase conversion of acetone to 3,5-xylenol in a single stage. US :3803 249 [ P], 1974-04-09.
  • 2DAVID RAJU B, RAMA RAO K S, SALVAPATHI G S, et al. Aromatization of isophorone to 3,5-xylenol over Cr203/SiO2 cat- alysts[J]. Appl Catal A, 2000, 193(1-2): 123-128.
  • 3HORNING E. Sulfur dehydrogenation of alkyleyclohexenones[ J]. J Amer Chem Soc, 1945,67 (8) : 1421-1422.
  • 4单绍军.PdCl_2脱氢合成3,5-二甲基苯酚[J].精细石油化工进展,2005,6(12):24-25. 被引量:4
  • 5DAVID RAJU B, RAMA RAO K S, SALVAPATHI G S, et al. Influence of K20 addition on the aromatization functionality of A1203-supported Cr203 catalysts in the trans- formation of isophorone [J]. Appl Catal A, 2001,209(1-2) :335-344.
  • 6ZHANG X, WANG R, YANG X, et al. Central composite experimental design applied to the catalytic aromatization of isophor- one to 3,5-xylenol[ J ]. Chemom Intell Lab Syst, 2007, 89 (1):45-50.
  • 7SAI PRASAD P S, DAVID RAJU B, RAMA RAO K S, et al. Selectivity improvement in the aromatization of isophorone on car- bon-covered alumina supported K20-Cr203 catalyst[ J]. J Mol Catal, 1993,78(2) : L19-L22.
  • 8SAI PRASAD P S, LINGAIAH N, SALVAPATHI G S, et al. Influence of surface polymeric oxide species on the product distri- bution in the aromatization of isophorone on alumine supported vanadia and molybdena catalysts [ J ]. React Kinet Catal Lett, 1996, 59 (1):151-157.
  • 9SALVAPATI G S, RAMANAMURTY K V, JANARDANARAO M, et al. Aromatization of isophorone to 3,5-xylenol[ J ]. Appl Catal, 1989,48 ( 2 ) : 223-233.
  • 10毛丽秋,李谦和,尹笃林.丙酮液相一步法合成异佛尔酮[J].湖南师范大学自然科学学报,2000,23(3):67-71. 被引量:13

二级参考文献8

共引文献49

同被引文献13

引证文献2

二级引证文献2

相关作者

内容加载中请稍等...

相关机构

内容加载中请稍等...

相关主题

内容加载中请稍等...

浏览历史

内容加载中请稍等...
;
使用帮助 返回顶部