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含单蝶状[2Fe2S]骨架的新型[FeFe]氢化酶模型物｛(μ-FcS)(μ-SMe)Fe_2(CO)_6｝的合成及其晶体结构 被引量：1

Synthesis and Crystal Structure of a Novel Single Butterfly-shaped Cluster[(μ-FcS)(μ-SMe)Fe_2(CO)_6]
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摘要 利用二茂铁基溴化镁(FcMgBr)与(μ-S2)Fe2(CO)6和MeI的反应,合成了一种新型的含二茂铁基[FeFe]氢化酶活性中心模型化合物——(μ-FcS)(μ-SMe)Fe2(CO)6(1),其结构经1H NMR,IR,元素分析和X-射线单晶衍射表征。1属于斜方晶系,Pna2(1)空间群,晶胞参数a=12.707(2),b=11.355(2),c=27.621(5),V=3 985.1(12)3,Z=8,Dc=1.813 g.cm-3,μ=2.395 mm-1,F(000)=2 176,R1=0.059 7,wR2=0.136 7。 A novel single butterfly-shaped cluster,（μ-FcS）（μ-SMe）Fe2（CO）6（1）,was synthesized by the reaction of ferrocenyl magnesium bromide（FcMgBr） with（μ-S2）Fe2（CO）6 and MeI.The structure was characterized by 1H NMR,IR,elemental analysis and X-ray single crystal diffraction.1 belongs to orthorhombic,space group Pna2（1） with a=12.707（2）,b=11.355（2）,c=27.621（5）,V=3 985.1（12）3,Z=8,Dc=1.813 g·cm-3,μ=2.395 mm-1,F（000）=2 176,R1=0.059 7,wR2=0.136 7.
作者 张磊 刘金庭
机构地区 浙江师范大学化学与生命科学学院 山东大学化学与化工学院
出处 《合成化学》 CAS CSCD 北大核心 2011年第6期727-729,733,共4页 Chinese Journal of Synthetic Chemistry
基金 浙江师范大学青年基金资助项目(KYJ06Y11004)
关键词 二茂铁 铁硫簇合物 [FeFe]氢化酶 合成 晶体结构 ferrocene sulfur-iron cluster hydrogenase synthesis crystal structure
分类号 O614.81 [理学—无机化学] O621.3 [理学—有机化学]
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参考文献10

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同被引文献17

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合成化学
2011年 第6期

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