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Highly Efficient Microwave-Assisted Substitution of β-Dicarbonyl Compounds with Secondary Alcohols Using Fluoroboric Acid as the Catalyst

Highly Efficient Microwave-Assisted Substitution of β-Dicarbonyl Compounds with Secondary Alcohols Using Fluoroboric Acid as the Catalyst
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摘要 The microwave-assisted substitution of β-dicarbonyl compounds with secondary alcohols has been achieved efficiently, using very cheap fluoroboric acid (HBF4) as the catalyst. For various β-dicarbonyl compounds and a series of secondary alcohols, the direct substitution gives high yields after only 5 min of microwave irradiation. The microwave-assisted substitution of β-dicarbonyl compounds with secondary alcohols has been achieved efficiently, using very cheap fluoroboric acid (HBF4) as the catalyst. For various β-dicarbonyl compounds and a series of secondary alcohols, the direct substitution gives high yields after only 5 min of microwave irradiation.
出处 《Chinese Journal of Chemistry》 SCIE CAS CSCD 2011年第10期2075-2080,共6页 中国化学(英文版)
基金 Project supported by the National Natural Science Foundation of China (No. 20902020), the Shanghai Pujiang Talent Program (No. 09PJ1403500) and the Fundamental Research Funds for the Central Universities.
关键词 SUBSTITUTION ALCOHOLS acid catalysis dicarbonyl compounds microwave chemistry substitution, alcohols, acid catalysis, dicarbonyl compounds, microwave chemistry
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