摘要
The microwave-assisted substitution of β-dicarbonyl compounds with secondary alcohols has been achieved efficiently, using very cheap fluoroboric acid (HBF4) as the catalyst. For various β-dicarbonyl compounds and a series of secondary alcohols, the direct substitution gives high yields after only 5 min of microwave irradiation.
The microwave-assisted substitution of β-dicarbonyl compounds with secondary alcohols has been achieved efficiently, using very cheap fluoroboric acid (HBF4) as the catalyst. For various β-dicarbonyl compounds and a series of secondary alcohols, the direct substitution gives high yields after only 5 min of microwave irradiation.
基金
Project supported by the National Natural Science Foundation of China (No. 20902020), the Shanghai Pujiang Talent Program (No. 09PJ1403500) and the Fundamental Research Funds for the Central Universities.