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Novel, Green, Simple and Uncatalyzed Route for High Yield Preparation of Benzaldehyde Glycol Acetal 被引量：4

Novel, Green, Simple and Uncatalyzed Route for High Yield Preparation of Benzaldehyde Glycol Acetal
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摘要 A simple approach for the condensation of benzaldehyde with ethylene glycol was adopted without employing any catalyst. The study reveals that factors including temperature, molar ratio of reactants, and the water removal significantly influence the conversion ratio of benzaldehyde. The results indicate that the use of optimal reaction conditions such as temperature and water removing exhibits more pronounced effects on the conversion ratio of benzaldehyde compared with the use of catalysts. In a word, a green and simple method for the condensation of aldehyde and menthandiol has been devised and investigated. A simple approach for the condensation of benzaldehyde with ethylene glycol was adopted without employing any catalyst. The study reveals that factors including temperature, molar ratio of reactants, and the water removal significantly influence the conversion ratio of benzaldehyde. The results indicate that the use of optimal reaction conditions such as temperature and water removing exhibits more pronounced effects on the conversion ratio of benzaldehyde compared with the use of catalysts. In a word, a green and simple method for the condensation of aldehyde and menthandiol has been devised and investigated.
作者 TANG Jia SONG Ji-yuan WANG Ge YANG Mu GUO Wan-chun
机构地区 School of Material Science and Engineering
出处 《Chemical Research in Chinese Universities》 SCIE CAS CSCD 2011年第5期799-802,共4页 高等学校化学研究（英文版）
基金 Supported by the National Natural Science Foundation of China(No.51073023) the Co-building Special Profect of Beijing Municipal Education Commission(China)
关键词 CONDENSATION BENZALDEHYDE Ethylene glycol Condensation Benzaldehyde Ethylene glycol
分类号 TQ655 [化学工程—精细化工] TQ546.5 [化学工程—煤化学工程]
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参考文献24

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同被引文献27

  • 1袁爱群,周泽广,白丽娟,马少妹,文衍宣,童张法.三聚磷酸二氢铝Ⅰ型二水物一步合成法及热分解动力学[J].化学工程,2007,35(1):32-36. 被引量：17
  • 2Xin L Y, Li M Q, Wei L D. Phosphotungstic acid encapsulated in metal-organic framework UiO-66:An effective catalyst for the selective oxidation of cyclopentene to glutaraldehyde[J]. Microporous and Mesoporous Materials, 2015, 211:73-81.
  • 3Andrea M N, Cecilia A M, Alejandra C N, et al. Dimerization of α-pinene, using phosphotungstic acid supported on SiOz as catalyst[J]. Current Catalysis, 2014, 3(2):240-243.
  • 4Liu Z G, Cao S, Wang S, et al. Silica-supported phosphotungstic acid as a novel heterogeneous catalyst for 1β-pinene polymerization[J]. Reaction Kinetics, Mechanisms and Catalysis, 2014, 111(2) :577-590.
  • 5Thenkrishnan K, Avala V D, Vidavalur S, et al. Regioselective acylation of 2-methoxy naphthalene catalyzed by supported 12-phosphotungstic acid[J]. Applied Catalysis A..General, 2014, 486 : 55-61.
  • 6Yang Z W, Zhao L, Lei Z Q. Quaternary ammonium salt functionalized methoxypolyethylene 1,2-propylene glycols- supported phosphotungstic acid catalyst for the esterification of carboxylic acids with alcohols [ J]. Catalysis Letters, 2014, 144(4):585-589.
  • 7Ajaikumar S, Pandurangan A. Reaction of benzaldehyde with various aliphatic 1,2-propylene 1,2-propylene glycols in the presence of hydrophobic A1-MCM-41:A convenient synthesis of cyclic acetals[J]. Journal of Molecular Catalysis A: Chemical, 2008, 290(1-2):35-43.
  • 8Zheng F C, Chen Q W, Hu L, et al. Synthesis of sulfonie acid-functionalized Fe3O4 nanopartieles as magnetically recyelable solid acid catalysts for acetatization reaction[J]. Dalton transactions, 2014, 43:1220-1227.
  • 9Laurianne M, Adrien B, Valerie M, et al. Glycerol acetals and ketals as bio-based solvents:Positioning in hansen and COSMO-RS spaces, volatility and stability towards hydrolysis and autoxidation[J]. Green Chemistry, 2015, 17: 1779- 1792.
  • 10Tao D J, Li Z M, Cheng Z, et al. Kinetics study of the ketalization reaction of cyclohexanone with 1,2-propylene 1,2 propylene glycol using Bronsted acidic ionic liquids as catalysts[J]. Ind. Eng. Chem. Res., 2012, 51(50):16263-16269.

引证文献4

二级引证文献8

Chemical Research in Chinese Universities
2011年 第5期

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