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Theoretical design and preparation of high thermal-stable jet fuel 被引量:2

Theoretical design and preparation of high thermal-stable jet fuel
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摘要 A high thermal-stable jet fuel design method was developed using composition-properties relations and basic specification properties of jet fuel. Tannery diagrams were provided to visualize relationships among three main components (n-paraffins, iso-paraffins, cycloparaffins, or aromatics) with four major specification properties (density, flash point, freezing point, net heat of combustion) and thermal sta- bility. An optimum chemical composition was established to meet performance requirements: n-paraffins 25%-45%, iso-paraffins 15%-30%, cycloparaffins 30%-50%, and aromatics 5%. The thermal stability test on four fuel samples with and without optimal composition indicated that the thermal stabilities of fuel samples with optimal composition are higher than RP-3 jet fuel, and that the theoretical design method is a reliable method to screen the basic oil for the high thermal-stable jet fuel. A high thermal-stable jet fuel design method was developed using composition-properties relations and basic specification properties of jet fuel. Tannery diagrams were provided to visualize relationships among three main components (n-paraffins, iso-paraffins, cycloparaffins, or aromatics) with four major specification properties (density, flash point, freezing point, net heat of combustion) and thermal stability. An optimum chemical composition was established to meet performance requirements: n-paraffins 25%–45%, iso-paraffins 15%–30%, cycloparaffins 30%–50%, and aromatics 5%. The thermal stability test on four fuel samples with and without optimal composition indicated that the thermal stabilities of fuel samples with optimal composition are higher than RP-3 jet fuel, and that the theoretical design method is a reliable method to screen the basic oil for the high thermal-stable jet fuel.
出处 《Science China Chemistry》 SCIE EI CAS 2008年第2期138-144,共7页 中国科学(化学英文版)
基金 National Hi-Tech Research and Development 863 Program of China (No. 2005AA723101) China Postdoctoral Science Foundation (No. 2005AA723101) Innovative Research Project of Petrochina Co. Ltd
关键词 JET fuel THERMAL stability composition-property RELATIONS composition DESIGN jet fuel thermal stability composition-property relations composition design
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