摘要
La substituted Ba(Mg_ 1/3Nb_ 2/3)O_3 ceramics was expected to enhance the 1∶2 ordering degree of B-site ions due to the existence of vacancies that promote cation movement and result in improvement of the Q_f value. The relation between the microstructure and microwave dielectric properties of Ba_ 1-xLa_ 2x/3(Mg_ 1/3Nb_ 2/3)O_3 ceramics was investigated. La substituted Ba(Mg_ 1/3Nb_ 2/3)O_3 ceramics can improve the sinterability of specimens. Both 1:2 ordering degree and grain size increase as A-site vacancies increase. This can be explained by the existence of vacancies that promote cation movement. The Q_f value increase with small La content, then decrease rapidly. The highest Q_f value achieved in this investigation is about 55000 GHz for Ba_ 0.995La_ 0.01/3(Mg_ 1/3Nb_ 2/3)O_3. The improvement of Q_f value with A-site vacancies is related to the increase of the degree of B-site ordering and grain size of the specimen.
La substituted Ba(Mg_ 1/3Nb_ 2/3)O_3 ceramics was expected to enhance the 1∶2 ordering degree of B-site ions due to the existence of vacancies that promote cation movement and result in improvement of the Q_f value. The relation between the microstructure and microwave dielectric properties of Ba_ 1-xLa_ 2x/3(Mg_ 1/3Nb_ 2/3)O_3 ceramics was investigated. La substituted Ba(Mg_ 1/3Nb_ 2/3)O_3 ceramics can improve the sinterability of specimens. Both 1:2 ordering degree and grain size increase as A-site vacancies increase. This can be explained by the existence of vacancies that promote cation movement. The Q_f value increase with small La content, then decrease rapidly. The highest Q_f value achieved in this investigation is about 55000 GHz for Ba_ 0.995La_ 0.01/3(Mg_ 1/3Nb_ 2/3)O_3. The improvement of Q_f value with A-site vacancies is related to the increase of the degree of B-site ordering and grain size of the specimen.
基金
ProjectsupportedbytheMinistryofEducationofChina
